Cellulose nanostructured films from pretreated açaí mesocarp fibers: physical, barrier, and tensile performance

Bibliographic Details
Title: Cellulose nanostructured films from pretreated açaí mesocarp fibers: physical, barrier, and tensile performance
Authors: Braga, Dayse Gonzaga, Abreu, Juliana Livian Lima de, Silva, Marcela Gomes da, Souza, Tiago Marcolino de, Dias, Matheus Cordazzo, Tonoli, Gustavo Henrique Denzin, Oliveira Neto, Cândido Ferreira de, Claro, Pedro Ivo Cunha, Gomes, Laércio Gouvêa, Bufalino, Lina
Source: CERNE. January 2021 27
Publisher Information: UFLA - Universidade Federal de Lavras, 2021.
Publication Year: 2021
Subject Terms: Alkaline pretreatment, Bleaching steps, Crystalline index, Barrier properties, Packaging
More Details: Background: During de-pulping of açai (Euterpe oleracea) for juice production in the Amazonia, large amounts of fibrous waste are daily discarded, a promising substrate for production of high-value cellulose nanofibrils. Therefore, this study sought to evaluate the modifications of açai surface fibers submitted to chemical pretreatment steps and compare the quality of nanostructured films produced with different cycles of mechanical nanofibrillation. Results: A 2-hour pretreatment (at 5% of NaOH) followed by two NaOH/H2O2 bleaching steps resulted in fibers with increased length and reduced diameter compared to raw fibers while preserving fiber integrity and cellulose I structure. The increase of fibers’ grinding cycles from 3 (minimum to gel point) to 21 (maximum suspension thickness) resulted in nanofibril films with higher crystallinity properties, uniform thickness, compacted morphology, and smoother surface. Nanofibril films formed after different numbers of passages exhibited similar mechanical strength, but distinct barrier properties. Conclusion: Açaí waste films produced with fibers submitted to 3 grinding cycles can be recommended for packaging applications that demand easily dissolving, such as instantaneous food. Oppositely, açaí fibers subjected to 21 cycles in grinder provide films suitable for water-resistant packaging, ideal for secondary coatings of papers and paperboards.
Document Type: article
File Description: text/html
Language: English
ISSN: 0104-7760
DOI: 10.1590/01047760202127012783
Access URL: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-77602021000100703
Rights: info:eu-repo/semantics/openAccess
Accession Number: edssci.S0104.77602021000100703
Database: SciELO
More Details
ISSN:01047760
DOI:10.1590/01047760202127012783
Published in:CERNE
Language:English