Process for the manufacture of wafers for solar cells at ambient pressure

Bibliographic Details
Title: Process for the manufacture of wafers for solar cells at ambient pressure
Document Number: 20120178262
Publication Date: July 12, 2012
Appl. No: 13/496498
Application Filed: September 15, 2010
Abstract: Solar cells are manufactured from P-type doped monocrystalline or polycrystalline silicon ingots by sawing wafers and applying an N-type doping. The wafers can be treated by etching them, in a plasma assisted process, with an etching gas containing or consisting of carbonyl fluoride. Hereby, the surface is roughened so that the degree of light reflection is reduced, or glass-like phosphorus-containing oxide coatings caused by phosphorus doping are removed. Carbonyl fluoride is also very suitable to selectively etch silicon oxide in silicon oxide/silicon composites.
Inventors: Riva, Marcello (Hannover, DE); Lopez Alonso, Elena (Dresden, DE); Linaschke, Dorit (Dresden, DE); Dani, Ines (Lichtenau, DE); Kaskel, Stefan (Dresden, DE)
Assignees: SOLVAY FLUOR GMBH (Hannover, DE)
Claim: 1. A method for manufacturing a wafer for a solar cell comprising a step of plasma-assisted etching of the wafer with an etching gas comprising carbonyl fluoride at a pressure which is equal to or greater than atmospheric pressure.
Claim: 2. The method of claim 1 wherein a silicon wafer for a solar cell is manufactured.
Claim: 3. The method of claim 1 wherein the method is performed at atmospheric pressure.
Claim: 4. The method according to claim 3 wherein the atmospheric pressure ranges between ambient pressure −300 Pa and ambient pressure +300 Pa.
Claim: 5. The method according to claim 1 wherein a wafer having a phosphorus-silicon-glass coating is etched to remove the phosphorus-silicon-glass coating.
Claim: 6. The method of claim 1 wherein silicon is etched.
Claim: 7. The method according to claim 6 wherein the surface of the wafer is a silicon surface which is etched to roughen the surface.
Claim: 8. The method according to claim 1 wherein silicon oxide or a silicon oxide/silicon composite on the surface of the wafer is treated via said plasma-assisted etching to selectively remove the silicon oxide.
Claim: 9. The method according to claim 1 wherein carbonyl fluoride is applied together with at least one gas selected from the group consisting of oxygen, nitrogen, N2O, helium, and argon.
Claim: 10. The method according to claim 9 wherein carbonyl fluoride is applied together with argon, nitrogen, or argon and nitrogen.
Claim: 11. The method of claim 10 wherein carbonyl fluoride, argon and nitrogen are introduced separately into an etching chamber.
Claim: 12. The method of claim 10 wherein carbonyl fluoride and a mixture of argon and nitrogen are introduced separately into an etching chamber.
Claim: 13. The method according to claim 1 wherein the wafer has a temperature ranging from 150° C. to 350° C.
Claim: 14. The method according to claim 10 wherein etching is performed with a gas mixture consisting of carbonyl fluoride, argon, and nitrogen.
Claim: 15. A method for manufacturing a solar cell wherein a wafer produced by the method according to claim 1 is used in said solar cell.
Claim: 16. The method according to claim 6 wherein the wafer has a temperature ranging from 150° C. to 350° C.
Current U.S. Class: 438/714
Current International Class: 01
Accession Number: edspap.20120178262
Database: USPTO Patent Applications
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Language:English