Poly[[aqua(μ2-oxalato)(μ2-2-oxidopyridinium-3-carboxylato)holmium(III)] monohydrate]

Bibliographic Details
Title: Poly[[aqua(μ2-oxalato)(μ2-2-oxidopyridinium-3-carboxylato)holmium(III)] monohydrate]
Authors: Hui-Lan Zhu, Hui-Ling Lai, Lu Han, Yi-Fan Luo, Rong-Hua Zeng
Source: Acta Crystallographica Section E, Vol 65, Iss 10, Pp m1217-m1218 (2009)
Publisher Information: International Union of Crystallography, 2009.
Publication Year: 2009
Collection: LCC:Crystallography
Subject Terms: Crystallography, QD901-999
More Details: In the title complex, {[Ho(C2O4)(C6H4NO3)(H2O)]·(H2O)}n, the HoIII ion is coordinated by three O atoms from two 2-oxidopyridinium-3-carboxylate ligands, four O atoms from two oxalate ligands and one water molecule in a distorted bicapped trigonal-prismatic geometry. The 2-oxidopyridinium-3-carboxylate and oxalate ligands link the HoIII ions into a layer in (100). These layers are further connected by intermolecular O—H...O hydrogen bonds involving the coordinated water molecules to assemble a three-dimensional supramolecular network. The uncoordinated water molecule is involved in N—H...O and O—H...O hydrogen bonds within the layer.
Document Type: article
File Description: electronic resource
Language: English
ISSN: 16005368
1600-5368
Relation: http://scripts.iucr.org/cgi-bin/paper?S1600536809036344; https://doaj.org/toc/1600-5368
DOI: 10.1107/S1600536809036344
Access URL: https://doaj.org/article/fd2e5bc487ca44639b4476abe87d3705
Accession Number: edsdoj.fd2e5bc487ca44639b4476abe87d3705
Database: Directory of Open Access Journals
More Details
ISSN:16005368
DOI:10.1107/S1600536809036344
Published in:Acta Crystallographica Section E
Language:English