Academic Journal
Photocontrollable Mixed-Valent States in Platinum-Halide Ladder Compounds
| Title: | Photocontrollable Mixed-Valent States in Platinum-Halide Ladder Compounds |
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| Authors: | Jun Ohara, Shoji Yamamoto |
| Source: | Applied Sciences, Vol 8, Iss 11, p 2126 (2018) |
| Publisher Information: | MDPI AG, 2018. |
| Publication Year: | 2018 |
| Collection: | LCC:Technology LCC:Engineering (General). Civil engineering (General) LCC:Biology (General) LCC:Physics LCC:Chemistry |
| Subject Terms: | photoinduced phase transition, halogen-bridged transition-metal complex, charge density wave, time-dependent Schrödinger equation, Technology, Engineering (General). Civil engineering (General), TA1-2040, Biology (General), QH301-705.5, Physics, QC1-999, Chemistry, QD1-999 |
| More Details: | Employing a two-orbital extended Peierls⁻Hubbard model, we demonstrate the photomanipulation of mixed-valent states in platinum-halide ladder compounds. There are two types of interchain valence arrangements, namely in-phase and out-of-phase types. The conversion of the in-phase structure to the out-of-phase structure is induced by photoirradiation, which is accelerated with increasing light intensity, while the reverse process hardly occurs. The out-of-phase arrangement is highly stabilized in the photoexcited states by the interchain electron transfer. |
| Document Type: | article |
| File Description: | electronic resource |
| Language: | English |
| ISSN: | 2076-3417 |
| Relation: | https://www.mdpi.com/2076-3417/8/11/2126; https://doaj.org/toc/2076-3417 |
| DOI: | 10.3390/app8112126 |
| Access URL: | https://doaj.org/article/b80b7156e5574222914216332e5daca6 |
| Accession Number: | edsdoj.b80b7156e5574222914216332e5daca6 |
| Database: | Directory of Open Access Journals |
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| ISSN: | 20763417 |
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| DOI: | 10.3390/app8112126 |
| Published in: | Applied Sciences |
| Language: | English |