Bibliographic Details
| Title: |
Direct Ink Writing of 3D Zn Structures as High‐Capacity Anodes for Rechargeable Alkaline Batteries |
| Authors: |
Cheng Zhu, Noah B. Schorr, Zhen Qi, Bryan R. Wygant, Damon E. Turney, Gautam G. Yadav, Marcus A. Worsley, Eric B. Duoss, Sanjoy Banerjee, Erik D. Spoerke, Anthony van Buuren, Timothy N. Lambert |
| Source: |
Small Structures, Vol 4, Iss 4, Pp n/a-n/a (2023) |
| Publisher Information: |
Wiley-VCH, 2023. |
| Publication Year: |
2023 |
| Collection: |
LCC:Physics
LCC:Chemistry |
| Subject Terms: |
direct ink writing, polymer gel electrolytes, Zn, NiOOH alkaline batteries, 3D-printed Zn anodes, Physics, QC1-999, Chemistry, QD1-999 |
| More Details: |
The relationship between structure and performance in alkaline Zn batteries is undeniable, where anode utilization, dendrite formation, shape change, and passivation issues are all addressable through anode morphology. While tailoring 3D hosts can improve the electrode performance, these practices are inherently limited by scaffolds that increase the mass or volume. Herein, a direct write strategy for producing template‐free metallic 3D Zn electrode architectures is discussed. Concentrated inks are customized to build designs with low electrical resistivity (5 × 10−4 Ω cm), submillimeter sizes (200 μm filaments), and high mechanical stability (Young's modulus of 0.1–0.5 GPa at relative densities of 0.28–0.46). A printed Zn lattice anode versus NiOOH cathode with an alkaline polymer gel electrolyte is then demonstrated. This Zn||NiOOH cell operates for over 650 cycles at high rates of 25 mA cm−2 with an average areal capacity of 11.89 mAh cm−2, a cumulative capacity of 7.8 Ah cm−2, and a volumetric capacity of 23.78 mAh cm−3. A thicker Zn anode achieves an ultrahigh areal capacity of 85.45 mAh cm−2 and a volumetric capacity of 81.45 mAh cm−3 without significant microstructural changes after 50 cycles. |
| Document Type: |
article |
| File Description: |
electronic resource |
| Language: |
English |
| ISSN: |
2688-4062 |
| Relation: |
https://doaj.org/toc/2688-4062 |
| DOI: |
10.1002/sstr.202200323 |
| Access URL: |
https://doaj.org/article/7ed1412b91fa4a42ab4c1cf99709ed05 |
| Accession Number: |
edsdoj.7ed1412b91fa4a42ab4c1cf99709ed05 |
| Database: |
Directory of Open Access Journals |
