Legacy and emerging organophosphorus flame retardants and plasticizers in indoor microenvironments from Guangzhou, South China

Bibliographic Details
Title: Legacy and emerging organophosphorus flame retardants and plasticizers in indoor microenvironments from Guangzhou, South China
Authors: Bin Tang, Christina Christia, Govindan Malarvannan, Yin-E. Liu, Xiao-Jun Luo, Adrian Covaci, Bi-Xian Mai, Giulia Poma
Source: Environment International, Vol 143, Iss , Pp 105972- (2020)
Publisher Information: Elsevier, 2020.
Publication Year: 2020
Collection: LCC:Environmental sciences
Subject Terms: Organophosphorus flame retardants (PFRs), Phthalates, Alternative plasticizers (APs), Indoor dust, Passive air sampling (PAS), Human exposure, Environmental sciences, GE1-350
More Details: Indoor dust has been extensively used for assessment of indoor contamination, especially for semi-volatile organic compounds (SVOCs). In the present study, the occurrence of four groups of SVOCs, i.e. organophosphorus flame retardants (PFRs), emerging PFRs (ePFRs), legacy phthalates (LPs), and alternative plasticizers (APs), was investigated in the indoor dust and air collected from floors, table surfaces, windows, and air conditioner (A/C) filters in bedrooms and offices in Guangzhou, South China. In bedrooms, A/C filter dust showed the highest median concentrations of PFRs (4670 ng/g) and ePFRs (586 ng/g), whilst the highest median concentrations of LPs and APs were found in floor (240,880 ng/g) and window dust (157,160 ng/g), respectively. In offices, A/C filter dust showed the highest median concentrations for PFRs (6750 ng/g) and APs (504,520 ng/g), while the highest ePFR median level was found in PC table dust (5810 ng/g) and LPs in floor dust (296,270 ng/g). Median air concentrations of PFRs, ePFRs, LPs, and APs were measured at 4.6, 0.12, 399, and 25 ng/m3 in bedrooms, and at 8.0, 0.05, 332, and 43 ng/m3 in offices, respectively. Tris(1-chloro-iso-propyl) phosphate (TCIPP) was the predominant PFRs/ePFRs in both dust and air. Di(2-ethylhexyl) phthalate (DEHP), di-iso-decyl phthalate (DIDP) and di-iso-nonyl phthalate (DINP) were the main LP/AP compounds in dust, whilst di-iso-butyl phthalate (DIBP) and di-n-butyl phthalate (DNBP) were the most abundant LPs/APs in air. A significant correlation (p 14. Among the investigated human exposure pathways (i.e. dust ingestion, dermal absorption, and air inhalation), dust ingestion was the predominant one for all chemicals. Human exposures of this magnitude to these chemicals through the investigated pathways was unlikely to present a health risk in the present study.
Document Type: article
File Description: electronic resource
Language: English
ISSN: 0160-4120
Relation: http://www.sciencedirect.com/science/article/pii/S0160412020319279; https://doaj.org/toc/0160-4120
DOI: 10.1016/j.envint.2020.105972
Access URL: https://doaj.org/article/76ca31bdf091432eabbdc822e8173d11
Accession Number: edsdoj.76ca31bdf091432eabbdc822e8173d11
Database: Directory of Open Access Journals
More Details
ISSN:01604120
DOI:10.1016/j.envint.2020.105972
Published in:Environment International
Language:English