Academic Journal
Enhanced Performance and Durability of Pore-Filling Membranes for Anion Exchange Membrane Water Electrolysis
| Title: | Enhanced Performance and Durability of Pore-Filling Membranes for Anion Exchange Membrane Water Electrolysis |
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| Authors: | Minyoung Lee, Jin-Soo Park |
| Source: | Membranes, Vol 14, Iss 12, p 269 (2024) |
| Publisher Information: | MDPI AG, 2024. |
| Publication Year: | 2024 |
| Collection: | LCC:Chemical technology LCC:Chemical engineering |
| Subject Terms: | pore-filling membrane, anion exchange membrane, anion-conducting electrolyte, water electrolysis, hydrogen, Chemical technology, TP1-1185, Chemical engineering, TP155-156 |
| More Details: | Four distinct pore-filling anion exchange membranes (PFAEMs) were prepared, and their mechanical properties, ion conductivity, and performance in anion exchange membrane water electrolysis (AEMWE) were evaluated. The fabricated PFAEMs demonstrated exceptional tensile strength, which was approximately 14 times higher than that of the commercial membrane, despite being nearly half as thin. Ion conductivity measurements revealed that acrylamide-based membranes outperformed benzyl-based ones, exhibiting 25% and 41% higher conductivity when using crosslinkers with two and three crosslinking sites, respectively. The AEMWE performance directly correlated with the hydrophilicity and ion exchange capacity (IEC) of the membranes. Specifically, AE_3C achieved the highest performance, supported by its superior IEC and ionic conductivity. Durability tests showed that AE_3C outlasted the commercial membrane, with a delayed voltage increase corresponding to its higher IEC, confirming the importance of increased ion-exchange functional groups in ensuring longevity. These results highlight the critical role of hydrophilic monomers and crosslinker structure in optimizing PFAEMs for enhanced performance and durability in AEMWE applications. |
| Document Type: | article |
| File Description: | electronic resource |
| Language: | English |
| ISSN: | 2077-0375 |
| Relation: | https://www.mdpi.com/2077-0375/14/12/269; https://doaj.org/toc/2077-0375 |
| DOI: | 10.3390/membranes14120269 |
| Access URL: | https://doaj.org/article/69b1996f6235425a98d5033e212a0b2f |
| Accession Number: | edsdoj.69b1996f6235425a98d5033e212a0b2f |
| Database: | Directory of Open Access Journals |
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| ISSN: | 20770375 |
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| DOI: | 10.3390/membranes14120269 |
| Published in: | Membranes |
| Language: | English |