Curing model and process parameters of cyanate ester resin based adhesives for spacecraft

Bibliographic Details
Title: Curing model and process parameters of cyanate ester resin based adhesives for spacecraft
Authors: HE Duan-peng, GAO Hong, XING Yan, LI Yan, WANG Xiang-ke
Source: Cailiao gongcheng, Vol 48, Iss 10, Pp 60-67 (2020)
Publisher Information: Journal of Materials Engineering, 2020.
Publication Year: 2020
Collection: LCC:Materials of engineering and construction. Mechanics of materials
Subject Terms: cyanate ester, curing temperature, curing time, curing degree, kissinger, flynn-wall-ozawa, crane, Materials of engineering and construction. Mechanics of materials, TA401-492
More Details: The non-isothermal reaction kinetics of cyanate ester system was investigated by dynamic differential scanning calorimetry (DSC). The analysis of non-isothermal data was carried out by using the model-fitting Kissinger, Flynn-Wall-Ozawa, and Crane methods. The results indicate that the apparent activation energy of the curing reaction is 101.3 kJ·mol-1 and 99.4 kJ·mol-1calculated from Kissinger and Flynn-Wall-Ozawa models, respectively. The reaction sequence of the adhesive is 0.92 calculated from Crane model. In addition, the relationship of the curing degree with the curing temperature and the curing time is established. The curing parameters are obtained by adopting "T-β" and "t-β" extrapolation, and the strength test proves the validity of the curing parameters designed in this paper. These results constitute a theoretical basis for the curing and application of the cyanate ester adhesives.
Document Type: article
File Description: electronic resource
Language: Chinese
ISSN: 1001-4381
Relation: http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.000931; https://doaj.org/toc/1001-4381
DOI: 10.11868/j.issn.1001-4381.2019.000931
Access URL: https://doaj.org/article/5f7f1ded2cd0460bb9d4d9450e908d54
Accession Number: edsdoj.5f7f1ded2cd0460bb9d4d9450e908d54
Database: Directory of Open Access Journals
More Details
ISSN:10014381
DOI:10.11868/j.issn.1001-4381.2019.000931
Published in:Cailiao gongcheng
Language:Chinese