Efficient removal of Tris(2-chloroethyl) phosphate by biochar derived from shrimp shell: Adsorption performance and mechanism study

Bibliographic Details
Title: Efficient removal of Tris(2-chloroethyl) phosphate by biochar derived from shrimp shell: Adsorption performance and mechanism study
Authors: Chenyu Yang, Chang Liu, Yile Yan, Lun Lu, Ruixue Ma, Xian Xiao, Yang Yu, Yuan Zhao, Yunjiang Yu, Liangzhong Li
Source: Ecotoxicology and Environmental Safety, Vol 254, Iss , Pp 114728- (2023)
Publisher Information: Elsevier, 2023.
Publication Year: 2023
Collection: LCC:Environmental pollution
LCC:Environmental sciences
Subject Terms: Tris(2-chloroethyl) phosphate, Shrimp shell biochar, Adsorption, Mechanism, Environmental pollution, TD172-193.5, Environmental sciences, GE1-350
More Details: Tris(2-chloroethyl) phosphate (TCEP) has been detected all over the world as a typical refractory organic phosphate, especially in groundwater. This work applied a calcium-rich biochar derived from shrimp shell as a low-cost adsorbent for TCEP removal. Based on the kinetics and isotherm studies, the adsorption of TCEP on biochar was monolayer adsorbed on a uniform surface, with SS1000 (the biochar was prepared at the carbonization temperature of 1000 °C) achieving the maximum adsorption capacity of 264.11 mg·g−1. The prepared biochar demonstrated stable TCEP removal ability throughout a wide pH range, in the presence of co-existing anions, and in diverse water bodies. A rapid removal rate of TCEP was observed during the adsorption process. When the dosage of SS1000 was 0.2 g·L−1, 95% of TCEP could be removed within the first 30 min. The mechanism analysis indicated that the calcium species and basic functional groups on the SS1000 surface were highly involved in the TCEP adsorption process.
Document Type: article
File Description: electronic resource
Language: English
ISSN: 0147-6513
Relation: http://www.sciencedirect.com/science/article/pii/S0147651323002324; https://doaj.org/toc/0147-6513
DOI: 10.1016/j.ecoenv.2023.114728
Access URL: https://doaj.org/article/d4f49134157a430ea5c1bd11d01492a3
Accession Number: edsdoj.4f49134157a430ea5c1bd11d01492a3
Database: Directory of Open Access Journals
More Details
ISSN:01476513
DOI:10.1016/j.ecoenv.2023.114728
Published in:Ecotoxicology and Environmental Safety
Language:English