Bibliographic Details
| Title: |
Electrodeposition kinetics of Ni-Mo alloy coating in choline-ethylene glycol deep eutectic system and its catalytic performance toward hydrogen evolution reaction |
| Authors: |
SHENG Shizhan, LI Lin, LI Wenchang, WANG Huihua |
| Source: |
Cailiao gongcheng, Vol 51, Iss 12, Pp 159-168 (2023) |
| Publisher Information: |
Journal of Materials Engineering, 2023. |
| Publication Year: |
2023 |
| Collection: |
LCC:Materials of engineering and construction. Mechanics of materials |
| Subject Terms: |
chcl-eg deep eutectic solvent, ni-mo alloy coating, deposition kinetics, electro catalysis, hydrogen evolution reaction(her), Materials of engineering and construction. Mechanics of materials, TA401-492 |
| More Details: |
The Ni-Mo alloy coatings were electrodeposited in the choline-ethylene glycol deep eutectic system(ChCl-EG) using Cu as the substrates, and the electrochemical impedance spectrum(EIS), scanning electronic microscopy(SEM), energy dispersive spectrometer(EDS) and X-ray diffraction (XRD) were employed to investigate the deposition kinetics of Ni-Mo alloy coatings. The influence of polarization potential on electrocatalytic HER performance of Ni-Mo alloy coatings was investigated. The results indicate that as the polarization potential increases, the Ni-Mo alloy coatings undergoes a process of evolution from nano Ni, Ni+MoO2 (MoO2Ni4) to Ni4Mo, indicating that potential is an important factor affecting the component change of Ni-Mo alloy coatings. Ni-Mo alloy coating fabricated at -1.4 V vs Ag displays excellent hydrogen evolution catalytic activity and stability, where the overpotential at 10 mA·cm-2 is only 51 mV, the Tafel slope is 48.7 mV·dec-1, and the decrease in hydrogen evolution overpotential is not significant(Δη100=11 mV) at 100 mA·cm-2 after 1000 cycles of catalytic cycling. |
| Document Type: |
article |
| File Description: |
electronic resource |
| Language: |
Chinese |
| ISSN: |
1001-4381 |
| Relation: |
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2022.000979; https://doaj.org/toc/1001-4381 |
| DOI: |
10.11868/j.issn.1001-4381.2022.000979 |
| Access URL: |
https://doaj.org/article/dc37baca1404427b90757d10de034783 |
| Accession Number: |
edsdoj.37baca1404427b90757d10de034783 |
| Database: |
Directory of Open Access Journals |
