Bibliographic Details
| Title: |
Crystal structure of 2-[4-(4-chlorophenyl)-1-(4-methoxyphenyl)-2-oxoazetidin-3-yl]benzo[de]isoquinoline-1,3-dione dimethyl sulfoxide monosolvate |
| Authors: |
Ísmail Çelik, Mehmet Akkurt, Aliasghar Jarrahpour, Javad Ameri Rad, Ömer Çelik |
| Source: |
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 2, Pp o129-o130 (2015) |
| Publisher Information: |
International Union of Crystallography, 2015. |
| Publication Year: |
2015 |
| Collection: |
LCC:Crystallography |
| Subject Terms: |
crystal structure, β-lactam ring, 1H-benzo[de]isoquinoline-1,3(2H)-dione group, disorder, azetidin-2-ones, Crystallography, QD901-999 |
| More Details: |
In the title solvated compound, C28H19N2O4·C2H6OS, the central β-lactam ring is almost planar (r.m.s. deviation = 0.002 Å). It makes dihedral angles of 1.92 (11), 83.23 (12) and 74.90 (10)° with the methoxy- and chlorophenyl rings and the ring plane of the 1H-benzo[de]isoquinoline-1,3(2H)-dione group [maximum deviation = 0.089 (1)], respectively. An intramolecular C—H...O hydrogen bond closes an S(6) ring and helps to establish the near coplanarity of the β-lactam and methoxybenzene rings. In the crystal, the components are linked by C—H...O hydrogen bonds, C—H...π interactions and aromatic π–π stacking interactions [centroid-to-centroid distances = 3.6166 (10) and 3.7159 (10) Å], resulting in a three-dimensional network, The dimethyl sulfoxide solvent molecule is disordered over two sets of sites in a 0.847 (2):0.153 (2) ratio. |
| Document Type: |
article |
| File Description: |
electronic resource |
| Language: |
English |
| ISSN: |
2056-9890
20569890 |
| Relation: |
http://scripts.iucr.org/cgi-bin/paper?S2056989015001425; https://doaj.org/toc/2056-9890 |
| DOI: |
10.1107/S2056989015001425 |
| Access URL: |
https://doaj.org/article/ad2ff21636cd4077807d1dec463df341 |
| Accession Number: |
edsdoj.2ff21636cd4077807d1dec463df341 |
| Database: |
Directory of Open Access Journals |
