| Title: |
Manipulation of metavalent bonding to stabilize metastable phase: A strategy for enhancing zT in GeSe |
| Authors: |
Yilun Huang, Tu Lyu, Manting Zeng, Moran Wang, Yuan Yu, Chaohua Zhang, Fusheng Liu, Min Hong, Lipeng Hu |
| Source: |
Interdisciplinary Materials, Vol 3, Iss 4, Pp 607-620 (2024) |
| Publisher Information: |
Wiley, 2024. |
| Publication Year: |
2024 |
| Collection: |
LCC:Materials of engineering and construction. Mechanics of materials |
| Subject Terms: |
band structure, GeSe, metastable phase, metavalent bonding, thermoelectric, Materials of engineering and construction. Mechanics of materials, TA401-492 |
| More Details: |
Abstract Exploration of metastable phases holds profound implications for functional materials. Herein, we engineer the metastable phase to enhance the thermoelectric performance of germanium selenide (GeSe) through tailoring the chemical bonding mechanism. Initially, AgInTe2 alloying fosters a transition from stable orthorhombic to metastable rhombohedral phase in GeSe by substantially promoting p‐state electron bonding to form metavalent bonding (MVB). Besides, extra Pb is employed to prevent a transition into a stable hexagonal phase at elevated temperatures by moderately enhancing the degree of MVB. The stabilization of the metastable rhombohedral phase generates an optimized bandgap, sharpened valence band edge, and stimulative band convergence compared to stable phases. This leads to decent carrier concentration, improved carrier mobility, and enhanced density‐of‐state effective mass, culminating in a superior power factor. Moreover, lattice thermal conductivity is suppressed by pronounced lattice anharmonicity, low sound velocity, and strong phonon scattering induced by multiple defects. Consequently, a maximum zT of 1.0 at 773 K is achieved in (Ge0.98Pb0.02Se)0.875(AgInTe2)0.125, resulting in a maximum energy conversion efficiency of 4.90% under the temperature difference of 500 K. This work underscores the significance of regulating MVB to stabilize metastable phases in chalcogenides. |
| Document Type: |
article |
| File Description: |
electronic resource |
| Language: |
English |
| ISSN: |
2767-441X |
| Relation: |
https://doaj.org/toc/2767-441X |
| DOI: |
10.1002/idm2.12170 |
| Access URL: |
https://doaj.org/article/dcc2dc9331034c47bc8ab44a40361029 |
| Accession Number: |
edsdoj.2dc9331034c47bc8ab44a40361029 |
| Database: |
Directory of Open Access Journals |
