Bibliographic Details
| Title: |
Enhancing the efficiency of polypyrrole-dodecylbenzene sulfonic acid in-tube solid-phase microextraction coating for analysis of nitrogen-containing pesticides in water environments |
| Authors: |
Rong Ma, Shuangshuang Yu, Yafang Li, Yan Lin, Xiaodong Ma |
| Source: |
Frontiers in Environmental Science, Vol 12 (2024) |
| Publisher Information: |
Frontiers Media S.A., 2024. |
| Publication Year: |
2024 |
| Collection: |
LCC:Environmental sciences |
| Subject Terms: |
in-tube solid-phase microextraction, polypyrrole, dodecylbenzene sulfonic acid, nitrogen-containing pesticides, environmental monitoring, coating optimization, Environmental sciences, GE1-350 |
| More Details: |
Background: With the growing use of nitrogen-containing pesticides in agriculture, their residues in the environment have raised significant public health concerns.Objective: This study aimed to develop a novel PPy-DBSA/IT-SPME coating to enhance the detection efficiency of polar nitrogen-containing pesticides in water matrices.Methods: The preparation conditions were optimized, including pyrrole concentration at 7.0 mol/L, DBSA concentration at 0.014 mol/L, oxidant concentration at 0.35 mol/L, and a coating cycle repeated 10 times. High-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was employed for detection.Results: The novel coating effectively adsorbed 19 different categories of polar nitrogen-containing pesticides, including sulfonylureas, triazolopyrimidines, diphenyl ether herbicides, benzoylurea insecticides, and phenylurea herbicides, with unadsorbed rates below 10%. The analytical method achieved an average recovery rate of 61.92% to 115.21%, with an RSD below 5.0%. Detection and quantification limits ranged from 0.012 to 0.524 μg/L and 0.127 to 5.243 μg/L, respectively.Conclusion: The developed method is green, efficient, simple, and cost-effective. It offers an environmentally friendly and user-friendly approach for the detection of polar nitrogen-containing pesticide residues, demonstrating good recovery and precision. This method holds potential for wide application in environmental monitoring and food safety. |
| Document Type: |
article |
| File Description: |
electronic resource |
| Language: |
English |
| ISSN: |
2296-665X |
| Relation: |
https://www.frontiersin.org/articles/10.3389/fenvs.2024.1350170/full; https://doaj.org/toc/2296-665X |
| DOI: |
10.3389/fenvs.2024.1350170 |
| Access URL: |
https://doaj.org/article/d2994e96c7be4ecd8d81943d1e30fd4d |
| Accession Number: |
edsdoj.2994e96c7be4ecd8d81943d1e30fd4d |
| Database: |
Directory of Open Access Journals |
