Bibliographic Details
| Title: |
Synthesis and Electron-Transporting Properties of N-Type Polymers with Cardanol-Based Side Chains |
| Authors: |
Jin Cheng, Hongyu Fu, Yifan Qiao, Xuming Xue, Pirada Sudprasert, Kenji Ogino |
| Source: |
Micromachines, Vol 15, Iss 12, p 1475 (2024) |
| Publisher Information: |
MDPI AG, 2024. |
| Publication Year: |
2024 |
| Collection: |
LCC:Mechanical engineering and machinery |
| Subject Terms: |
cardanol-based, n-type polymer, electron-transporting properties, Mechanical engineering and machinery, TJ1-1570 |
| More Details: |
We synthesized n-type polymers poly{[N,N′-bis(2-octyldodecyl)-naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5′-(2,2′-bithiophene)} [P(NDI2OD-T2)] and poly{[N,N′-bis(3-(4-cardanol)propyl)-naphthalene-1,4,5,8-tetracarboxylic diimide]-alt-[5,5′-bis(2-thienyl)-2,2′-bithiophene]} [P(NDICL-T2)] with cardanol-based side chains via Stille coupling to enhance electron mobility. Replacing the 2-octyldodecyl side chain with cardanol in P(NDICL-T2) improved electron mobility due to increased chain flexibility and ordered packing. Lower glass transition temperature (tg), red-shifted UV-vis absorption, results from crystalline structure analysis, indicating tighter lamellar spacing and enhanced molecular ordering, and smoother surface morphology confirmed the enhanced intermolecular interactions and uniform film formation. |
| Document Type: |
article |
| File Description: |
electronic resource |
| Language: |
English |
| ISSN: |
2072-666X |
| Relation: |
https://www.mdpi.com/2072-666X/15/12/1475; https://doaj.org/toc/2072-666X |
| DOI: |
10.3390/mi15121475 |
| Access URL: |
https://doaj.org/article/0e764a5fa71b4ffab2d6fa6b1fcc2f4f |
| Accession Number: |
edsdoj.0e764a5fa71b4ffab2d6fa6b1fcc2f4f |
| Database: |
Directory of Open Access Journals |
