Bibliographic Details
Title: |
Preparation of multifunctional chitosan derivative containing 10-undecenoyl and galloyl groups and its application in styrene-butadiene rubber/silica composites |
Authors: |
Xiaojiang Xie, Lihao Wu, Jizhong Huang, Jingwei He, Fang Liu |
Source: |
Carbohydrate Polymer Technologies and Applications, Vol 7, Iss , Pp 100468- (2024) |
Publisher Information: |
Elsevier, 2024. |
Publication Year: |
2024 |
Collection: |
LCC:Biochemistry |
Subject Terms: |
Chitosan derivatives, Synthesis, Structural characteristics, Multifunctional modifier, SBR/silica composites, Biochemistry, QD415-436 |
More Details: |
The traditional small molecular rubber antioxidants have the shortcomings of single function, toxicity, and heavy dependence on non-renewable fossil resources, which limits their green, high-efficiency, and sustainable development in the rubber industry. To address this problem, in this work, we first developed a chitosan derivative containing 10-undecenoyl groups (COS-UC) and then combined it with the natural small molecular antioxidant gallic acid (GA) to prepare chitosan derivative containing 10-undecenoyl and galloyl groups (COS-UC-GA). The obtained COS-UC-GA was used as multifunctional modifier and applied in styrene-butadiene rubber (SBR)/silica composites. The effects of COS-UC-GA on the curing characteristics, crosslinking density, morphology, mechanical properties, and interfacial interaction of SBR/silica composites were explored in detail. The results indicated that the COS-UC-GA can effectively accelerate the vulcanization process of SBR/silica compounds, promote the uniform dispersion of silica, improve the mechanical properties of SBR/silica composites, and significantly enhance the interfacial interaction between the silica and rubber. This research provides a new perspective for developing green and eco-friendly multifunctional modifiers, which not only contributes to the comprehensive utilization of biomass resources, but also can promote the green development of the rubber industry. |
Document Type: |
article |
File Description: |
electronic resource |
Language: |
English |
ISSN: |
2666-8939 |
Relation: |
http://www.sciencedirect.com/science/article/pii/S2666893924000483; https://doaj.org/toc/2666-8939 |
DOI: |
10.1016/j.carpta.2024.100468 |
Access URL: |
https://doaj.org/article/0174a7f255254049b33bd07bf49d7120 |
Accession Number: |
edsdoj.0174a7f255254049b33bd07bf49d7120 |
Database: |
Directory of Open Access Journals |