Superconductivity in ZrB12 under High Pressure

Bibliographic Details
Title: Superconductivity in ZrB12 under High Pressure
Authors: Zexiao Zhang, Xu Zheng, Hanshan Luo, Chan Gao, Xiaowei Xue, Jingcheng Zhu, Ruobin Li, Changqing Jin, Xiaohui Yu
Source: Metals, Vol 14, Iss 9, p 1082 (2024)
Publisher Information: MDPI AG, 2024.
Publication Year: 2024
Collection: LCC:Mining engineering. Metallurgy
Subject Terms: transition metal borides, hard material, superconductivity, high pressure, zirconium dodecaboride, Mining engineering. Metallurgy, TN1-997
More Details: Transition metal borides have emerged as pivotal players in various fields. In addition to their exceptional properties such as high hardness, a high melting point, and corrosion resistance, certain compounds exhibit remarkable characteristics including superconductivity, magnetism, electrical conductivity, and catalytic activity. Among these compounds, ZrB12 has garnered significant attention due to its unique physicochemical properties. However, previous research on ZrB12 has predominantly focused on its mechanical behavior while overlooking the electron-electron interactions of the superconducting state. In this paper, resistance characterization of ZrB12 under high-pressure conditions was conducted to further investigate its superconductivity. Our research findings indicate that ZrB12 maintains its superconductivity within a pressure range of 0 to 1.5 GPa and is classified as a type 2 superconductor. Additionally, the results confirm the anisotropic nature of ZrB12’s superconductivity. As the pressure increases, the superconducting transition temperature undergoes a gradual decrease. Remarkably, ZrB12 exhibits metallic behavior under pressures up to 31.4 GPa. The observed decline in superconductivity in ZrB12 can be ascribed to the intensified influence of Zr’s movement on phonon dispersion, ultimately leading to a reduction in carrier concentration.
Document Type: article
File Description: electronic resource
Language: English
ISSN: 2075-4701
Relation: https://www.mdpi.com/2075-4701/14/9/1082; https://doaj.org/toc/2075-4701
DOI: 10.3390/met14091082
Access URL: https://doaj.org/article/0169ed76fe4e4b53852638b201701633
Accession Number: edsdoj.0169ed76fe4e4b53852638b201701633
Database: Directory of Open Access Journals
Full text is not displayed to guests.
More Details
ISSN:20754701
DOI:10.3390/met14091082
Published in:Metals
Language:English