Bibliographic Details
| Title: |
Hexakis(dimethyl sulfoxide-κO)nickel(II) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II) |
| Authors: |
Meiju Niu, Shumei Fan, Guihua Liu |
| Source: |
Acta Crystallographica Section E, Vol 68, Iss 1, Pp m67-m67 (2012) |
| Publisher Information: |
International Union of Crystallography, 2012. |
| Publication Year: |
2012 |
| Collection: |
LCC:Crystallography |
| Subject Terms: |
Crystallography, QD901-999 |
| More Details: |
The reaction of NiCl2·6H2O with sodium 2,2-dicyanoethene-1,1-dithiolate [Na2(i-mnt)] in dimethyl sulfoxide produces the title complex, [Ni(C2H6OS)6][Ni(C4N2S2)2]. There is half each of an [Ni(C2H6OS)6]2− complex anion and an [Ni{(CH3)2SO}6]2+ complex cation in the asymmetric unit. The i-mnt ligand coordinates in a bidentate manner to the Ni atom in the anion through the two chelating S atoms in an approximate square-planar geometry. The Ni atom in the complex cation has an octahedral coordination environment with six dimethyl sulfoxide molecules as ligands. |
| Document Type: |
article |
| File Description: |
electronic resource |
| Language: |
English |
| ISSN: |
16005368
1600-5368 |
| Relation: |
http://scripts.iucr.org/cgi-bin/paper?S1600536811053827; https://doaj.org/toc/1600-5368 |
| DOI: |
10.1107/S1600536811053827 |
| Access URL: |
https://doaj.org/article/c013511e07054d8c99fd1ba833862dd4 |
| Accession Number: |
edsdoj.013511e07054d8c99fd1ba833862dd4 |
| Database: |
Directory of Open Access Journals |
