Multi-step stochastic mechanism of polarization reversal in orthorhombic ferroelectrics

Bibliographic Details
Title: Multi-step stochastic mechanism of polarization reversal in orthorhombic ferroelectrics
Authors: Genenko, Yuri A., Zhang, Maohua, Vorotiahin, Ivan S., Khachaturyan, Ruben, Liu, Yi-Xuan, Li, Jia-Wang, Wang, Ke, Koruza, Jurij
Publication Year: 2021
Collection: Condensed Matter
Subject Terms: Condensed Matter - Materials Science
More Details: A stochastic model of electric field-driven polarization reversal in orthorhombic ferroelectrics is advanced, providing a description of their temporal electromechanical response. The theory accounts for all possible parallel and sequential switching events. Application of the model to the simultaneous measurements of polarization and strain kinetics in a lead-free orthorhombic (K,Na)NbO3-based ferroelectric ceramic over a wide timescale of 7 orders of magnitude allowed identification of preferable polarization switching paths, fractions of individual switching processes, and their activation fields. Particularly, the analysis revealed substantial contributions of coherent non-180{\deg} switching events, which do not cause macroscopic strain and thus mimic 180{\deg} switching processes.
Document Type: Working Paper
DOI: 10.1103/PhysRevB.104.184106
Access URL: http://arxiv.org/abs/2109.00406
Accession Number: edsarx.2109.00406
Database: arXiv
More Details
DOI:10.1103/PhysRevB.104.184106