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We investigate the distribution of major and trace elements in apatite crystals hosted in granular alkaline rocks composed mainly of leucite and clinopyroxene, representative of the hypabyssal crystallization of a magma body in the Quaternary ultra-potassic Colli Albani Volcanic District (CAVD), which was emplaced into thick limestone units along the Tyrrhenian margin of Italy. Results show that the analyzed crystals are the SrO-richest (up to 4.6 wt%) fluorapatite (F =2.6-3.7 wt%) of the Italian alkaline rocks. The strontium enrichment is caused by the lack of other Sr-compatible mineral phases, such as plagioclase, alkali feldspar and melilite, in these leucite- and clinopyroxene-bearing rocks. The studied samples show core-rim zoning with rims enriched in Si, S, and REE whereas the cores are enriched in Ca and P. The LREE-oxides contents of apatite, reaching 4.2 wt%, represent more than 95% of the total REE budget; SiO2 contents range from 1.3 to 3.6 wt%, and SO3 concentrations between 0.6 and 1.4 wt%. |
