Upper limits for undetected trace species in the stratosphere of Titan

Bibliographic Details
Title: Upper limits for undetected trace species in the stratosphere of Titan
Authors: Nixon, Conor A., Achterberg, Richard K., Teanby, Nicholas A., Irwin, Patrick G. J., Flaud, Jean-Marie, Kleiner, Isabelle, Dehayem-Kamadjeu, Alix, Brown, Linda R., Sams, Robert L., Bézard, Bruno, Coustenis, Athena, Ansty, Todd M., Mamoutkine, Andrei, Vinatier, Sandrine, Bjoraker, Gordon L., Jennings, Donald E., Romani, Paul. N., Flasar, F. Michael
Source: Faraday Discuss., 2010, Vol. 147, pp. 65-81
Publication Year: 2011
Collection: Astrophysics
Subject Terms: Astrophysics - Earth and Planetary Astrophysics
More Details: In this paper we describe a first quantitative search for several molecules in Titan's stratosphere in Cassini CIRS infrared spectra. These are: ammonia (NH3), methanol (CH3OH), formaldehyde (H2CO), and acetonitrile (CH3CN), all of which are predicted by photochemical models but only the last of which observed, and not in the infrared. We find non-detections in all cases, but derive upper limits on the abundances from low-noise observations at 25{\deg}S and 75{\deg}N. Comparing these constraints to model predictions, we conclude that CIRS is highly unlikely to see NH3 or CH3OH emissions. However, CH3CN and H2CO are closer to CIRS detectability, and we suggest ways in which the sensitivity threshold may be lowered towards this goal.
Comment: 11 pages plus 6 figure files
Document Type: Working Paper
DOI: 10.1039/c003771k
Access URL: http://arxiv.org/abs/1103.0297
Accession Number: edsarx.1103.0297
Database: arXiv
More Details
DOI:10.1039/c003771k