Bibliographic Details
| Title: |
C20H4(C4F8)3: A Fluorine-Containing Annulated Corannulene that Is a Better Electron Acceptor Than C60. |
| Authors: |
Kuvychko, Igor V., Dubceac, Cristina, Deng, Shihu H. M., Wang, Xue‐Bin, Granovsky, Alexander A., Popov, Alexey A., Petrukhina, Marina A., Strauss, Steven H., Boltalina, Olga V. |
| Source: |
Angewandte Chemie International Edition; Jul2013, Vol. 52 Issue 29, p7505-7508, 4p |
| Subject Terms: |
ANNULATION, CORANNULENE, ELECTROPHILES, ELECTRONS, HALOGENS |
| Abstract: |
At sixes and sevens: The reaction of corannulene with 35 equivalents of 1,4‐C4F8I2 is an efficient and a relatively selective process that yields two main products in which six H atoms are substituted with three C4F8 moieties that form six‐ and seven‐membered rings. Low‐temperature photoelectron spectroscopy showed the electron affinity of the major isomer (shown) exceeds that of C60 (2.74±0.02 and 2.689±0.008 eV, respectively). [ABSTRACT FROM AUTHOR] |
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| Database: |
Complementary Index |
