Title: |
Pd(ii) conjugated chitosan nanofibre mats for application in Heck cross-coupling reactionsElectronic supplementary information (ESI) available. See DOI: 10.1039/c1cc14717j. |
Authors: |
Bradshaw, Michael, Zou, Jianli, Byrne, Lindsay, Swaminathan Iyer, K., Stewart, Scott G., Raston, Colin L. |
Source: |
Chemical Communications; Nov2011, Vol. 47 Issue 45, p12292-12294, 3p |
Subject Terms: |
CHITOSAN, NANOFIBERS, PALLADIUM catalysts, HECK reaction, BIOCONJUGATES, CATALYSTS recycling, BENZENE, ACRYLATES, COMPOSITE materials |
Abstract: |
Pd(ii)–chitosan composite nanofibres of 62 ± 9 nm diameter are efficient catalysts for Heck cross-coupling reactions. Using a model reaction of iodo-benzene and n-butyl acrylate, we demonstrate that this material can be used as a recyclable catalytic support with a very low loading of palladium (0.17 mol% Pd). [ABSTRACT FROM AUTHOR] |
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Database: |
Complementary Index |