Bibliographic Details
| Title: |
Triple‐structured polyvinylidene fluoride‐based composite films with high conductivity and EM shielding properties. |
| Authors: |
Zhou, Teng, Tan, Yanyan, Yang, Renyuan, Xu, Yuhuan, Zhan, Xiao, Du, Jingyu, Diao, Kunlan, Qin, Shuhao, Zhang, Daohai |
| Source: |
Polymer Composites; 3/10/2025, Vol. 46 Issue 4, p3264-3277, 14p |
| Abstract: |
Functionalized thin films with excellent flexibility and conductivity can meet the current requirements for electromagnetic(EM) shielding materials. In this paper, 2D transitions metal carbide and nitride nanomaterials Ti3C2Tx MXene were prepared by chemical exfoliation, and PVDF/MWCNTs/3 wt%/RGO@Fe3O4@ AgNWs‐10 based on PVDF/MWCNTs‐3 wt%/RGO@Fe3O4@AgNWs‐10, The samples were prepared through a simple solution mixing process followed by vacuum‐assisted filtration (VAF), and PVDF/MWCNTs/MXene/RGO@Fe3O4@AgNWs three‐layer PVDF‐based composite films, which were analyzed for electrical conductivity and EM shielding properties, which increased and then decreased with the rise in the Ti3C2Tx MXene content, in which the highest electrical conductivity of the three‐layer composite films of M3/MX‐10/R@F@Ag was obtained when the Ti3C2Tx MXene addition amount reached 10 mL as 3.9 × 103 S/m, the EMI SET is 54.9 dB, the EMI SEA is 44.8 dB, the absorption loss is 81.6%, and the SSEt of the M3/MX‐10/R@F@Ag three‐layer composite film is the highest 1672.5 dB/(cm−2·g). And the SEA/SER ratios of the M3/MX‐X/R@F@Ag three‐layer composite films are all greater than 1. The result shows that the EM attenuation mechanism of the M3/MX‐X/R@F@Ag three‐layer composite films is primarily driven by absorption loss and that the incorporation of Ti3C2Tx Mxene improves the EM shielding performance of the composite films. The relatively novel exploration of the performance study and structural design of the M3/MX‐X/R@F@Ag three‐layer EM shielding composite film provides structural design and research ideas for the application of the new MXenes material in EM shielding composites. Highlights: The addition of Ti3C2Tx MXene will generate more conductive network nodulesA complete 3D conductive network is constructed in the membraneThis paper discusses the influence of Ti3C2Tx MXene on EM shieldingMultiple internal reflections of EMW between Ti3C2Tx MXene 2D nanosheetsThe EM shielding mechanism of the film is discussed from the angle of 3D [ABSTRACT FROM AUTHOR] |
|
Copyright of Polymer Composites is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| Database: |
Complementary Index |
