Bibliographic Details
| Title: |
Revisiting Bond Breaking and Making in EuCo2P2: Where are the Electrons? |
| Authors: |
Yannello, Vincent, Guillou, Francois, Yaroslavtsev, Alexander A., Tener, Zachary P., Wilhelm, Fabrice, Yaresko, Alexander N., Molodtsov, Serguei L., Scherz, Andreas, Rogalev, Andrei, Shatruk, Michael |
| Source: |
Chemistry - A European Journal; 4/23/2019, Vol. 25 Issue 23, p5865-5869, 5p |
| Subject Terms: |
ELECTRONS, X-ray absorption, PHASE transitions, X-ray spectroscopy, CHARGE exchange, ELECTRON density |
| Abstract: |
X‐ray absorption spectroscopy (XAS) was used to elucidate changes in the electronic structure caused by the pressure‐induced structural collapse in EuCo2P2. The spectral changes observed at the L3‐edge of Eu and K‐edges of Co and P suggest electron density redistribution, which contradicts the formal charges calculated from the commonly used Zintl–Klemm concept. Quantum‐chemical calculations show that, despite the increase in the oxidation state of Eu and the formation of a weak P−P bond in the high‐pressure phase, the electron transfer from the Eu 4f orbitals to the hybridized 5d and 6s states causes strengthening of the Eu−P and P−P bonds. These changes explain the increased electron density on P atoms, deduced from the P K‐edge XAS spectra. This work shows that the formal electron counting schemes do not provide an adequate description of changes associated with phase transitions in metallic systems with substantial mixing of the electronic states. [ABSTRACT FROM AUTHOR] |
|
Copyright of Chemistry - A European Journal is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| Database: |
Complementary Index |
