| Title: |
Thermally induced 1D to 2D polymer conversion accompanied by major packing changes in single-crystal-to-single-crystal transformation. |
| Authors: |
Singh, Ashutosh S., Ali, Amjad, Tiwari, Ranjay K., Behera, Jogendra N., Sun, Shih-Sheng, Chandrasekhar, Vadapalli |
| Source: |
CrystEngComm; 5/7/2018, Vol. 20 Issue 17, p2346-2350, 5p |
| Subject Terms: |
HYDROGEN bonding, SINGLE crystals, COORDINATION polymers |
| Abstract: |
An unprecedented thermal response is observed in [(4,4′-bpe·2H+)(HSO4−)2] (1), a hydrogen-bonded 1D coordination polymer. While 1 was photostable to irradiation at 365 nm, upon heating at 70 °C for 1 h, it transformed into 1·ph, a 2D polymer, through single-crystal-to-single-crystal transformation (SCSCT). In this conversion, a series of bonds are broken and re-formed simultaneously, leading to major changes in the packing pattern which is quite rare in SCSCT. [ABSTRACT FROM AUTHOR] |
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| Database: |
Complementary Index |
