| Title: |
A Convenient Method for Catalytic Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl)trimethoxyborate. |
| Authors: |
Tsuyuka Sugiishi, Daisuke Kawauchi, Mizuki Sato, Tatsuya Sakai, Hideki Amii |
| Source: |
Synthesis; 2017, Vol. 49 Issue 8, p1874-1878, 5p |
| Subject Terms: |
AROMATIC compounds, CATALYTIC activity, ETHYLATION, COPPER catalysts, CATALYSIS, ARYL iodides |
| Abstract: |
A method for the copper-catalyzed pentafluoroethylation of aryl iodides using potassium (pentafluoroethyl)trimethoxyborate has been developed. The borate was found to be a convenient pentafluoroethyl source. In parallel, it was found that the solvent, as well as ligand, makes significant impact on the catalytic perfluoroalkylations. [ABSTRACT FROM AUTHOR] |
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| Database: |
Complementary Index |
