Bibliographic Details
| Title: |
catena-Poly[[[tripyridinecopper(II)]-μ- m-phenylenedioxydiacetato] monohydrate]. |
| Authors: |
Xian-Lan Hong1,2, Yi-Zhi Li1, Guo-Qing Jiang1,3, Jun-Feng Bai1 llyyjz@nju.edu.cn |
| Source: |
Acta Crystallographica: Section E. Aug2005, Vol. 61 Issue 8, pm1556-m1558. 3p. 3 Diagrams, 2 Charts. |
| Subject Terms: |
*COPPER, *PHENYLACETATES, *LIGAND binding (Biochemistry), *LIGANDS (Chemistry), *HYDROGEN bonding, *BENZENE, *PYRIDINE |
| Abstract: |
In the title compound, [Cu(C10H8O6)(C5H5N)3]·H2O, the coordination geometry around the CuII atom is distorted square-pyramidal, and the Cu—N bond at the apical position lies on a twofold axis. The m-phenylenedioxydiacetate ligand also has twofold symetry and acts as bridge to link Cu atoms to form infinite chains along the c axis. The solvent water molecule connects two adjacent carboxylate groups of the m-phenylenedioxydiacetates on the same chain via hydrogen bonds. [ABSTRACT FROM AUTHOR] |
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| Database: |
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