Creation, stabilization, and investigation at ambient pressure of pressure-induced superconductivity in Bi0.5Sb1.5Te3.

Bibliographic Details
Title: Creation, stabilization, and investigation at ambient pressure of pressure-induced superconductivity in Bi0.5Sb1.5Te3.
Authors: Liangzi Deng1 ldeng2@central.uh.edu, Busheng Wang2, Halbert, Clayton3, Schulze, Daniel J.1, Gooch, Melissa1, Bontke, Trevor1, Ting-Wei Kuo1,4, Xin Shi1, Shaowei Song1, Salke, Nilesh5, Hung-Duen Yang4, Zhifeng Ren1, Hemley, Russell J.3,5,6, Zurek, Eva2, Prasankumar, Rohit P.7, Ching-Wu Chu1 cwchu@uh.edu
Source: Proceedings of the National Academy of Sciences of the United States of America. 2/11/2025, Vol. 122 Issue 6, p1-8. 18p.
Subject Terms: *DIAMOND anvil cell, *SUPERCONDUCTIVITY, *CRITICAL temperature, *THERMAL stability, *SEMICONDUCTORS
Abstract: In light of breakthroughs in superconductivity under high pressure, and considering that record critical temperatures (Tcs) across various systems have been achieved under high pressure, the primary challenge for higher Tc should no longer solely be to increase Tc under extreme conditions but also to reduce, or ideally eliminate, the need for applied pressure in retaining pressure-induced or -enhanced superconductivity. The topological semiconductor Bi0.5Sb1.5Te3 (BST) was chosen to demonstrate our approach to addressing this challenge and exploring its intriguing physics. Under pressures up to ~50 GPa, three superconducting phases (BST-I,-II, and -III) were observed. A superconducting phase in BST-I appears at ~4 GPa, without a structural transition, suggesting the possible topological nature of this phase. Using the pressure-quench protocol (PQP) recently developed by us, we successfully retained this pressure-induced phase at ambient pressure and revealed the bulk nature of the state. Significantly, this demonstrates recovery of a pressure-quenched sample from a diamond anvil cell at room temperature with the pressure-induced phase retained at ambient pressure. Other superconducting phases were retained in BST-II and -III at ambient pressure and subjected to thermal and temporal stability testing. Superconductivity was also found in BST with Tc up to 10.2 K, the record for this compound series. While PQP maintains superconducting phases in BST at ambient pressure, both depressurization and PQP enhance its Tc, possibly due to microstructures formed during these processes, offering an added avenue to raise Tc. These findings are supported by our density-functional theory calculations. [ABSTRACT FROM AUTHOR]
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Database: Academic Search Complete
More Details
ISSN:00278424
DOI:10.1073/pnas.2423102122
Published in:Proceedings of the National Academy of Sciences of the United States of America
Language:English