Bibliographic Details
| Title: |
Multifunctional Organometallic Compounds: An Interesting Luminescent NLO‐Active Alkynylplatinum (II) Complex. |
| Authors: |
Colombo, Alessia1 (AUTHOR), Dragonetti, Claudia1 (AUTHOR), Fagnani, Francesco1 (AUTHOR) francesco.fagnani@unimi.it, Roberto, Dominique1 (AUTHOR), Guerchais, Véronique2 (AUTHOR), Roisnel, Thierry2 (AUTHOR), Fantacci, Simona3 (AUTHOR), Marinotto, Daniele4 (AUTHOR) |
| Source: |
European Journal of Inorganic Chemistry. 12/12/2024, Vol. 27 Issue 35, p1-7. 7p. |
| Subject Terms: |
*SECOND harmonic generation, *NONLINEAR optics, *ORGANOMETALLIC compounds, *SINGLE crystals, *ELEMENTAL analysis, *PHOTOLUMINESCENCE measurement |
| Abstract: |
Reaction of 4‐methylphenylacetylide with the known chlorido platinum(II) complex bearing the cyclometalated 1,3‐bis(pyridin‐2‐yl)‐4,6‐difluoro‐benzene ligand afforded a novel alkynyl platinum(II) complex, 1, that was fully characterized by elemental analysis, NMR and UV‐visible spectroscopies, by photoluminescence measurements, and by computational modelling. Its structure was determined by X‐ray diffraction studies on a single crystal whereas its second‐order nonlinear optical (NLO) properties were determined in solution by the Electric‐Field Induced Second Harmonic generation method. The novel multifunctional complex 1 is characterized by good luminescence properties, like the related chlorido Pt(II) complex, but by a much higher second‐order NLO response. [ABSTRACT FROM AUTHOR] |
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