| Title: |
Crystal Structure of Bis(1-butyl-1-methypyrrolidinium) Perthiodicarbonate Complex. |
| Authors: |
Pinaud, Noël1 (AUTHOR) noel.pinaud@u-bordeaux.fr, Danten, Yann2 (AUTHOR) yann.danten@u-bordeaux.fr, Marchivie, Mathieu3 (AUTHOR) mathieu.marchivie@u-bordeaux.fr, Besnard, Marcel2 (AUTHOR) marcel.besnard@u-bordeaux.fr, Cabaço, Isabel4 (AUTHOR) isabelcabaco@tecnico.ulisboa.pt, Guillon, Jean5 (AUTHOR) jean.guillon@u-bordeaux.fr |
| Source: |
Molbank. Sep2024, Vol. 2024 Issue 3, pM1849. 6p. |
| Subject Terms: |
*CARBON disulfide, *X-ray diffraction, *SPACE groups, *CRYSTAL structure, *IONIC liquids |
| Abstract: |
Bis(1-butyl-1-methypyrrolidinium) perthiodicarbonate was obtained by the reaction of carbon disulfide with 1-butyl-1-methypyrrolidinium acetate ([BmPyrro][Ac]) in the liquid phase. Structural characterization of this original complex was achieved by single-crystal X-ray diffraction (SCXRD) analysis. The asymmetric unit of the title compound, C2S6·2C9H20N, consisted of two crystallographically 1-methyl-1-butyl pyrrolidinium cations and one perthiodicarbonate anion. The complex C2S6·2C9H20N crystallized in the monoclinic space group, C 2/c, and possessed the following cell parameters: a = 16.0970(10) Å, b = 14.7140(9) Å, c = 12.3280(8) Å, α = 90°, β = 112.3730(12)°, γ = 90°, V = 2700.11 Å3, and Z = 8, Z' = 0.5. [ABSTRACT FROM AUTHOR] |
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