Green Approaches for the Extraction of Banana Peel Phenolics Using Deep Eutectic Solvents.

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Title: Green Approaches for the Extraction of Banana Peel Phenolics Using Deep Eutectic Solvents.
Authors: Cegledi, Ena1 (AUTHOR) ena.cegledi@pbf.unizg.hr, Dobroslavić, Erika1 (AUTHOR) imagnabosca@gmail.com, Pedisić, Sandra2 (AUTHOR) sandra.pedisic@pbf.unizg.hr, Magnabosca, Ivan1 (AUTHOR) marija.zoric888@gmail.com, Zorić, Marija1 (AUTHOR) r.pavic54@gmail.com, Pavić, Rina1 (AUTHOR) otilija.stargl1@gmail.com, Šuto, Marija1 (AUTHOR), Štargl, Otilija1 (AUTHOR), Repajić, Maja1 (AUTHOR), Elez Garofulić, Ivona1 (AUTHOR) ena.cegledi@pbf.unizg.hr
Source: Molecules. Aug2024, Vol. 29 Issue 15, p3672. 16p.
Subject Terms: *SOLVENT extraction, *HYDROXYCINNAMIC acids, *BIOACTIVE compounds, *FLAVONOIDS, *EXTRACTION techniques, *CHOLINE chloride
Abstract: Banana peels, comprising about 35% of the fruit's weight, are often discarded, posing environmental and economic issues. This research focuses on recycling banana peel waste by optimizing advanced extraction techniques, specifically microwave-assisted (MAE) and ultrasound-assisted extraction (UAE), for the isolation of phenolic compounds. A choline chloride-based deep eutectic solvent (DES) with glycerol in a 1:3 ratio with a water content of 30% (w/w) was compared to 30% ethanol. Parameters, including sample-to-solvent ratio (SSR), extraction time, and temperature for MAE or amplitude for UAE, were varied. Extracts were analyzed for hydroxycinnamic acid (HCA) and flavonoid content, and antioxidant activity using FRAP and ABTS assays. DES outperformed ethanol, with HCA content ranging from 180.80 to 765.92 mg/100 g and flavonoid content from 96.70 to 531.08 mg/100 g, accompanied by higher antioxidant activity. Optimal MAE conditions with DES were an SSR of 1:50, a temperature of 60 °C, and a time of 10 min, whereas an SSR of 1:60, time of 5 min, and 75% amplitude were optimal for UAE. The polyphenolic profile of optimized extracts comprised 19 individual compounds belonging to the class of flavonols, flavan-3-ols, and phenolic acids. This study concluded that DESs, with their superior extraction efficiency and environmental benefits, are promising solvents for the extraction of high-value bioactive compounds from banana peels and offer significant potential for the food and pharmaceutical industries. [ABSTRACT FROM AUTHOR]
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  Data: Green Approaches for the Extraction of Banana Peel Phenolics Using Deep Eutectic Solvents.
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  Data: <searchLink fieldCode="AR" term="%22Cegledi%2C+Ena%22">Cegledi, Ena</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> ena.cegledi@pbf.unizg.hr</i><br /><searchLink fieldCode="AR" term="%22Dobroslavić%2C+Erika%22">Dobroslavić, Erika</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> imagnabosca@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Pedisić%2C+Sandra%22">Pedisić, Sandra</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> sandra.pedisic@pbf.unizg.hr</i><br /><searchLink fieldCode="AR" term="%22Magnabosca%2C+Ivan%22">Magnabosca, Ivan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> marija.zoric888@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Zorić%2C+Marija%22">Zorić, Marija</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> r.pavic54@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Pavić%2C+Rina%22">Pavić, Rina</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> otilija.stargl1@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Šuto%2C+Marija%22">Šuto, Marija</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Štargl%2C+Otilija%22">Štargl, Otilija</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Repajić%2C+Maja%22">Repajić, Maja</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Elez+Garofulić%2C+Ivona%22">Elez Garofulić, Ivona</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> ena.cegledi@pbf.unizg.hr</i>
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  Data: <searchLink fieldCode="JN" term="%22Molecules%22">Molecules</searchLink>. Aug2024, Vol. 29 Issue 15, p3672. 16p.
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  Data: Banana peels, comprising about 35% of the fruit's weight, are often discarded, posing environmental and economic issues. This research focuses on recycling banana peel waste by optimizing advanced extraction techniques, specifically microwave-assisted (MAE) and ultrasound-assisted extraction (UAE), for the isolation of phenolic compounds. A choline chloride-based deep eutectic solvent (DES) with glycerol in a 1:3 ratio with a water content of 30% (w/w) was compared to 30% ethanol. Parameters, including sample-to-solvent ratio (SSR), extraction time, and temperature for MAE or amplitude for UAE, were varied. Extracts were analyzed for hydroxycinnamic acid (HCA) and flavonoid content, and antioxidant activity using FRAP and ABTS assays. DES outperformed ethanol, with HCA content ranging from 180.80 to 765.92 mg/100 g and flavonoid content from 96.70 to 531.08 mg/100 g, accompanied by higher antioxidant activity. Optimal MAE conditions with DES were an SSR of 1:50, a temperature of 60 °C, and a time of 10 min, whereas an SSR of 1:60, time of 5 min, and 75% amplitude were optimal for UAE. The polyphenolic profile of optimized extracts comprised 19 individual compounds belonging to the class of flavonols, flavan-3-ols, and phenolic acids. This study concluded that DESs, with their superior extraction efficiency and environmental benefits, are promising solvents for the extraction of high-value bioactive compounds from banana peels and offer significant potential for the food and pharmaceutical industries. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Molecules is the property of MDPI and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/molecules29153672
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