Bibliographic Details
| Title: |
Na ion-exchanged zirconium phosphate crystal with high calcium ion selectivity. |
| Authors: |
Hayashi, Fumitaka1 (AUTHOR), Shirasu, Yuka1 (AUTHOR), Fujisawa, Kazunori2 (AUTHOR), Tipplook, Mongkol2 (AUTHOR), Yamada, Tetsuya1,2 (AUTHOR), Teshima, Katsuya1,2 (AUTHOR) teshima@shinshu-u.ac.jp |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 7/21/2024, Vol. 53 Issue 27, p11252-11256. 5p. |
| Subject Terms: |
*ZIRCONIUM phosphate, *CALCIUM ions, *CALCIUM, *CRYSTALS, *ION exchange (Chemistry) |
| Abstract: |
We demonstrate hydrothermally grown sodium hydrogen zirconium phosphate ((Na,H)–ZrP) crystals exhibiting high calcium ion selectivity. The standard Gibbs free energies for Ca2+ exchange on (Na,H)–ZrP and γ-type ZrP were estimated to be −10.1 and −4.69 kJ mol−1, respectively. The high Ca2+ selectivity of (Na,H)–ZrP could be attributed to the size matching between the ion exchange site of (Na,H)–ZrP and Ca2+. [ABSTRACT FROM AUTHOR] |
|
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| Database: |
Academic Search Complete |
