| Title: |
An unexpected isomerisation of Isoquinuclidines. |
| Authors: |
Moura, Rebeca G.1 (AUTHOR), Batista, Patrick R.1 (AUTHOR), Ducati, Lucas C.1 (AUTHOR), Yamaguchi, Lydia F.1 (AUTHOR), Marzorati, Liliana1 (AUTHOR) lmarzora@iq.usp.br |
| Source: |
Journal of Physical Organic Chemistry. Sep2023, Vol. 36 Issue 9, p1-8. 8p. |
| Subject Terms: |
*ISOMERIZATION, *DIELS-Alder reaction |
| Abstract: |
The Diels–Alder reaction of three chiral dihydro‐2H‐[2,3‐a]oxazolopyridines with N‐methylmaleimide afforded the corresponding chiral cycloadducts as diastereomeric mixtures. In the presence of a solvent, some of the originally formed adducts underwent isomerisation to new isoquinuclidines. [ABSTRACT FROM AUTHOR] |
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