| Title: |
Spectroscopic and Crystallographic Characterization of the R3N+−C−H⋅⋅⋅X Interaction. |
| Authors: |
Capilato, Joseph N.1 (AUTHOR), Harry, Stefan A.1 (AUTHOR), Siegler, Maxime A.1 (AUTHOR), Lectka, Thomas1 (AUTHOR) lectka@jhu.edu |
| Source: |
Chemistry - A European Journal. 2/7/2022, Vol. 28 Issue 8, p1-8. 8p. |
| Subject Terms: |
*LEWIS bases, *HYDROGEN bonding, *ATOMS |
| Abstract: |
As appreciation for nonclassical hydrogen bonds has progressively increased, so have efforts to characterize these interesting interactions. Whereas several kinds of C−H hydrogen bonds have been well‐studied, much less is known about the R3N+−C−H⋅⋅⋅X variety. Herein, we present crystallographic and spectroscopic evidence for the existence of these interactions, with special relevance to Selectfluor chemistry. Of particular note is the propensity for Lewis bases to engage in nonclassical hydrogen bonding over halogen bonding with the electrophilic F atom of Selectfluor. Further, the first examples of 1H NMR experiments detailing R3N+−C−H⋅⋅⋅X (X=O, N) hydrogen bonds are described. [ABSTRACT FROM AUTHOR] |
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| Database: |
Academic Search Complete |
