Title: |
Corrosion mitigation in desalination plants by ammonium-based ionic liquid. |
Authors: |
Deyab, M. A.1 (AUTHOR) hamadadeiab@yahoo.com, Mohsen, Q.2 (AUTHOR) |
Source: |
Scientific Reports. 11/2/2021, Vol. 11 Issue 1, p1-9. 9p. |
Subject Terms: |
*SULFATE-reducing bacteria, *CORROSION in alloys, *SALINE waters, *SURFACE morphology, *SEAWATER corrosion |
Abstract: |
CuNi (90:10) alloy is widely used in desalination plants. CuNi alloy corrosion in sulfide-containing seawater is the fundamental problem in the desalination industry. Here we have confronted this difficulty by using ammonium-based ionic liquid (Diethyl (2-methoxyethyl)-methyl ammonium Bis(fluorosulfonyl)imide) [DEMEMA][FSI]. The results revealed that the [DEMEMA][FSI] can suppress Cu–Ni alloy corrosion in a solution of (3.5% NaCl + 10 ppm sulphide) with an efficiency of 98.4% at 120 ppm. This has been estimated by electrochemistry and gravimetry. Furthermore, [DEMEMA][FSI] inhibits the growth of sulfate-reducing bacteria SRB in saline water. Surface morphology testing confirmed [DEMEMA][FSI] adsorption on Cu–Ni surface alloys. In addition, quantum calculations have been used to theoretically predict inhibition efficiency [DEMEMA][FSI]. [ABSTRACT FROM AUTHOR] |
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Database: |
Academic Search Complete |