Impact of the Enzyme Charge on the Production and Morphological Features of Cellulose Nanofibrils.

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Title: Impact of the Enzyme Charge on the Production and Morphological Features of Cellulose Nanofibrils.
Authors: Henríquez-Gallegos, Sergio1,2 (AUTHOR) anandrade@udec.cl, Albornoz-Palma, Gregory1 (AUTHOR) gralbornoz@udec.cl, Andrade, Andrea2 (AUTHOR), Soto, Carolina1 (AUTHOR) carosotoh@udec.cl, Pereira, Miguel1,3 (AUTHOR) miguelpereira@udec.cl
Source: Polymers (20734360). Oct2021, Vol. 13 Issue 19, p3238. 1p.
Subject Terms: *DEGREE of polymerization, *CELLULOSE, *ENZYMES, *TENSILE strength
Abstract: The available research does not allow specific relationships to be established between the applied enzymatic-mechanical treatment, the degree of polymerization, and the characteristics of the cellulose nanofibrils (CNFs) produced. This work aims to establish specific relationships between the intensity of enzymatic treatment, the degree of polymerization of the cellulose, the morphology of CNFs, and the tensile strength of the CNF films. It is determined that the decrease in the degree of polymerization plays an essential role in the fibrillation processes of the cell wall to produce CNFs and that there is a linear relationship between the degree of polymerization and the length of CNFs, which is independent of the type of enzyme, enzyme charge, and intensity of the applied mechanical treatment. In addition, it is determined that the percentage of the decrease in the degree of polymerization of CNFs due to mechanical treatment is irrespective of the applied enzyme charge. Finally, it is shown that the aspect ratio is a good indicator of the efficiency of the fibrillation process, and is directly related to the mechanical properties of CNF films. [ABSTRACT FROM AUTHOR]
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  Data: Impact of the Enzyme Charge on the Production and Morphological Features of Cellulose Nanofibrils.
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  Data: <searchLink fieldCode="JN" term="%22Polymers+%2820734360%29%22">Polymers (20734360)</searchLink>. Oct2021, Vol. 13 Issue 19, p3238. 1p.
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  Data: *<searchLink fieldCode="DE" term="%22DEGREE+of+polymerization%22">DEGREE of polymerization</searchLink><br />*<searchLink fieldCode="DE" term="%22CELLULOSE%22">CELLULOSE</searchLink><br />*<searchLink fieldCode="DE" term="%22ENZYMES%22">ENZYMES</searchLink><br />*<searchLink fieldCode="DE" term="%22TENSILE+strength%22">TENSILE strength</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: The available research does not allow specific relationships to be established between the applied enzymatic-mechanical treatment, the degree of polymerization, and the characteristics of the cellulose nanofibrils (CNFs) produced. This work aims to establish specific relationships between the intensity of enzymatic treatment, the degree of polymerization of the cellulose, the morphology of CNFs, and the tensile strength of the CNF films. It is determined that the decrease in the degree of polymerization plays an essential role in the fibrillation processes of the cell wall to produce CNFs and that there is a linear relationship between the degree of polymerization and the length of CNFs, which is independent of the type of enzyme, enzyme charge, and intensity of the applied mechanical treatment. In addition, it is determined that the percentage of the decrease in the degree of polymerization of CNFs due to mechanical treatment is irrespective of the applied enzyme charge. Finally, it is shown that the aspect ratio is a good indicator of the efficiency of the fibrillation process, and is directly related to the mechanical properties of CNF films. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.3390/polym13193238
    Languages:
      – Code: eng
        Text: English
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      – SubjectFull: DEGREE of polymerization
        Type: general
      – SubjectFull: CELLULOSE
        Type: general
      – SubjectFull: ENZYMES
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      – SubjectFull: TENSILE strength
        Type: general
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      – TitleFull: Impact of the Enzyme Charge on the Production and Morphological Features of Cellulose Nanofibrils.
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            NameFull: Henríquez-Gallegos, Sergio
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            NameFull: Albornoz-Palma, Gregory
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            NameFull: Andrade, Andrea
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            NameFull: Soto, Carolina
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            NameFull: Pereira, Miguel
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          Dates:
            – D: 01
              M: 10
              Text: Oct2021
              Type: published
              Y: 2021
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              Value: 13
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