Bibliographic Details
| Title: |
Nickel-Catalyzed anti -Selective Alkyne Functionalization Reactions. |
| Authors: |
Bottcher, Sydney E.1 (AUTHOR) dwilger@samford.edu, Hutchinson, Lauren E.1 (AUTHOR), Wilger, Dale J.1 (AUTHOR) |
| Source: |
Synthesis. 2020, Vol. 52 Issue 19, p2807-2820. 14p. |
| Subject Terms: |
*ISOMERIZATION, *STEREOSELECTIVE reactions |
| Abstract: |
Nickel-catalyzed anti -selective alkyne functionalization reactions are reviewed with an emphasis on the mechanisms that lead to their observed stereoselectivity. Since the isomerization of alkenylnickel species plays a key role in a large number of these reactions, the potential mechanisms for these processes are also described in detail. 1 Introduction 2 anti -Selective Hydroarylation 3 anti -Selective Carboborylation 4 anti -Selective Dicarbofunctionalization 4.1 Carbocyanative Cyclization 4.2 Cyclization with Aryl Donors 4.3 Cyclization with CO2 4.4 Intermolecular Dicarbofunctionalization 5 anti -Selective Carbosulfonylation 6 Alkenylnickel Isomerization 7 Conclusions [ABSTRACT FROM AUTHOR] |
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| Database: |
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