Bibliographic Details
| Title: |
Photoredox Catalysis Mediated Application of Methyl Fluorosulfonyldifluoroacetate as the CF2CO2R Radical Source. |
| Authors: |
Wei Yu1, Xiu-Hua Xu1, Feng-Ling Qing1,2 flq@mail.sioc.ac.cn |
| Source: |
Organic Letters. Oct2016, Vol. 18 Issue 19, p5130-5133. 4p. |
| Subject Terms: |
*PHOTOCATALYSIS, *METHYLATION, *CHEMICAL reagents, *METHYL groups, *ACETATES, *RADICALS (Chemistry) |
| Abstract: |
A new application of trifluoromethylating reagent, methyl fluorosulfonyldifluoroacetate (FO2SCF2CO2Me, Chen's reagent), as the carbomethoxydifluoromethylating reagent under visible light photoredox conditions is reported. The visible-light-induced reaction of FO2SCF2CO2Me with unactivated alkenes, styrenes, or heteroarenes affords a variety of carbomethoxydifluoromethylated products. [ABSTRACT FROM AUTHOR] |
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| Database: |
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