Bibliographic Details
| Title: |
Comparison Kinetic Analysis between Coats-Redfern and Criado’s Master Plot on Pyrolysis of Horse Manure |
| Authors: |
Bo Yu Li, Meng Yang Tee, Kie Seng Nge, Andrew Kay Lup Ng, William Woei Fong Chong, Jo-Han Ng, Guo Ren Mong |
| Source: |
Chemical Engineering Transactions, Vol 106 (2023) |
| Publisher Information: |
AIDIC Servizi S.r.l., 2023. |
| Publication Year: |
2023 |
| Collection: |
LCC:Chemical engineering
LCC:Computer engineering. Computer hardware |
| Subject Terms: |
Chemical engineering, TP155-156, Computer engineering. Computer hardware, TK7885-7895 |
| More Details: |
As a commonly used approach in kinetics analysis, the model-fit method is typically employed to determine the feedstock’s reaction model undergoing thermal decomposition. There are several methods in the literature to obtaining the reaction model. However, very little research has been done to compare the discrepancies resulting from different model-fitting methods. In this study, two model-fitting methods, Coats-Redfern (CR) and Criado master plot were used to evaluate horse manure pyrolysis's kinetic reaction model. The feedstock was pyrolyzed in a thermogravimeter at a temperature ramp rate of 10 °C/min under N2 atmosphere. Both methods indicated that the 2-D Diffusion (Anti-Jander) reaction model was most suited to describe the pyrolysis reaction, illustrating that the reaction rate was limited by the diffusion of components through the product layer at the interface of feedstock. The other two parameters of kinetic triplets as determined from the CR method are activation energy, Ea at 68.3 kJ/mol and pre-exponential factor, A at 4.16×106 s-1. The Ea value in this work is much lower than that obtained through the model-free method. |
| Document Type: |
article |
| File Description: |
electronic resource |
| Language: |
English |
| ISSN: |
2283-9216 |
| Relation: |
https://www.cetjournal.it/index.php/cet/article/view/14273; https://doaj.org/toc/2283-9216 |
| DOI: |
10.3303/CET23106213 |
| Access URL: |
https://doaj.org/article/fa4e0ed9f03a4faeb6bd5f4ccceb1692 |
| Accession Number: |
edsdoj.fa4e0ed9f03a4faeb6bd5f4ccceb1692 |
| Database: |
Directory of Open Access Journals |
