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An integrated process by ultrasonic enhancement in the deep eutectic solvents system for extraction and separation of chlorogenic acid from Eucommia ulmoides leaves

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Title: An integrated process by ultrasonic enhancement in the deep eutectic solvents system for extraction and separation of chlorogenic acid from Eucommia ulmoides leaves
Authors: Yue Meng, Xiaoyu Sui, Xu Pan, Ying Yang, Huimin Sui, Tao Xu, Honglian Zhang, Tingting Liu, Jicheng Liu, Pengling Ge
Source: Ultrasonics Sonochemistry, Vol 99, Iss , Pp 106588- (2023)
Publisher Information: Elsevier, 2023.
Publication Year: 2023
Collection: LCC:Chemistry
LCC:Acoustics. Sound
Subject Terms: Deep eutectic solvents, Eucommia ulmoides leaves, Chlorogenic acid, Ultrasonic wave-enhanced, Macroporous adsorption resin, Chemistry, QD1-999, Acoustics. Sound, QC221-246
More Details: This study established an integrated process for the extraction and enrichment of chlorogenic acid (CGA) from Eucommia ulmoides leaves in a deep eutectic solvent system via ultrasonic wave-enhanced adsorption and desorption practices utilizing macroporous resins. Although deep eutectic solvents (DESs) have the advantages of chemical stability, good dissolving capacity, and nonvolatilization, routine solvent recovery operations are not suitable for subsequent separation in this solvent system. Based on the above characteristics, this study integrated the extraction and enrichment processes, in which DESs extracts directly loaded onto the macroporous adsorption resin, avoiding the loss of target components in solvent recovery and redissolution processes. The screening results of solvents and resin types further showed that choline chloride-malic acid (1:1) was the optimal DES, and the NKA-II resin had high adsorption and elution performance for CGA. The viscosities of the DESs were much higher than those of water and conventional organic solvents; thus, the mass transfer resistance was large, which could also affect the adsorption behaviour of the macroporous resin. The thermal and mechanical effects of ultrasound could effectively enhance the efficiency of the mass transfer, adsorption, and desorption in the DES systems. When compared to no sonication treatment, the CGA adsorption at various ultrasonic powers (120–600 W) was examined. At optimal ethanol concentration (60%), the effect of the ultrasonic treatment on the recovery of the DESs (water eluting process) and the desorption capability of CGA were confirmed. The use of three volumes of water elution could recover the DESs without loss of CGA. The adsorption process significantly differed depending on the ultrasonic settings, and the absorption balance time and experimental adsorption capacity at equilibrium were enhanced. Additionally, the adsorption procedure of the NKA-II macroporous resin for CGA under ultrasonic treatment could be clarified by the pseudo second order kinetic equation and the Freundlich isotherm model. Thermodynamic and dynamic parameters indicated that physical adsorption was the main process of the entire procedure, and it was a spontaneous, exothermic, and entropy-reducing physical adsorption process. This study potentially indicates that the use of ultrasonication, as a high-efficiency, environmentally friendly method, can enhance the features of the macroporous resin to better purify target chemicals from a DES extract.
Document Type: article
File Description: electronic resource
Language: English
ISSN: 1350-4177
Relation: http://www.sciencedirect.com/science/article/pii/S1350417723003000; https://doaj.org/toc/1350-4177
DOI: 10.1016/j.ultsonch.2023.106588
Access URL: https://doaj.org/article/5d06118d09074e428c42baebca2e4333
Accession Number: edsdoj.5d06118d09074e428c42baebca2e4333
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  Data: An integrated process by ultrasonic enhancement in the deep eutectic solvents system for extraction and separation of chlorogenic acid from Eucommia ulmoides leaves
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  Data: <searchLink fieldCode="AR" term="%22Yue+Meng%22">Yue Meng</searchLink><br /><searchLink fieldCode="AR" term="%22Xiaoyu+Sui%22">Xiaoyu Sui</searchLink><br /><searchLink fieldCode="AR" term="%22Xu+Pan%22">Xu Pan</searchLink><br /><searchLink fieldCode="AR" term="%22Ying+Yang%22">Ying Yang</searchLink><br /><searchLink fieldCode="AR" term="%22Huimin+Sui%22">Huimin Sui</searchLink><br /><searchLink fieldCode="AR" term="%22Tao+Xu%22">Tao Xu</searchLink><br /><searchLink fieldCode="AR" term="%22Honglian+Zhang%22">Honglian Zhang</searchLink><br /><searchLink fieldCode="AR" term="%22Tingting+Liu%22">Tingting Liu</searchLink><br /><searchLink fieldCode="AR" term="%22Jicheng+Liu%22">Jicheng Liu</searchLink><br /><searchLink fieldCode="AR" term="%22Pengling+Ge%22">Pengling Ge</searchLink>
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  Data: Ultrasonics Sonochemistry, Vol 99, Iss , Pp 106588- (2023)
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  Data: This study established an integrated process for the extraction and enrichment of chlorogenic acid (CGA) from Eucommia ulmoides leaves in a deep eutectic solvent system via ultrasonic wave-enhanced adsorption and desorption practices utilizing macroporous resins. Although deep eutectic solvents (DESs) have the advantages of chemical stability, good dissolving capacity, and nonvolatilization, routine solvent recovery operations are not suitable for subsequent separation in this solvent system. Based on the above characteristics, this study integrated the extraction and enrichment processes, in which DESs extracts directly loaded onto the macroporous adsorption resin, avoiding the loss of target components in solvent recovery and redissolution processes. The screening results of solvents and resin types further showed that choline chloride-malic acid (1:1) was the optimal DES, and the NKA-II resin had high adsorption and elution performance for CGA. The viscosities of the DESs were much higher than those of water and conventional organic solvents; thus, the mass transfer resistance was large, which could also affect the adsorption behaviour of the macroporous resin. The thermal and mechanical effects of ultrasound could effectively enhance the efficiency of the mass transfer, adsorption, and desorption in the DES systems. When compared to no sonication treatment, the CGA adsorption at various ultrasonic powers (120–600 W) was examined. At optimal ethanol concentration (60%), the effect of the ultrasonic treatment on the recovery of the DESs (water eluting process) and the desorption capability of CGA were confirmed. The use of three volumes of water elution could recover the DESs without loss of CGA. The adsorption process significantly differed depending on the ultrasonic settings, and the absorption balance time and experimental adsorption capacity at equilibrium were enhanced. Additionally, the adsorption procedure of the NKA-II macroporous resin for CGA under ultrasonic treatment could be clarified by the pseudo second order kinetic equation and the Freundlich isotherm model. Thermodynamic and dynamic parameters indicated that physical adsorption was the main process of the entire procedure, and it was a spontaneous, exothermic, and entropy-reducing physical adsorption process. This study potentially indicates that the use of ultrasonication, as a high-efficiency, environmentally friendly method, can enhance the features of the macroporous resin to better purify target chemicals from a DES extract.
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