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Generation of a μ-1,2-hydroperoxo FeIIIFeIII and a μ-1,2-peroxo FeIVFeIII Complex

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Title: Generation of a μ-1,2-hydroperoxo FeIIIFeIII and a μ-1,2-peroxo FeIVFeIII Complex
Authors: Stephan Walleck, Thomas Philipp Zimmermann, Henning Hachmeister, Christian Pilger, Thomas Huser, Sagie Katz, Peter Hildebrandt, Anja Stammler, Hartmut Bögge, Eckhard Bill, Thorsten Glaser
Source: Nature Communications, Vol 13, Iss 1, Pp 1-11 (2022)
Publisher Information: Nature Portfolio, 2022.
Publication Year: 2022
Collection: LCC:Science
Subject Terms: Science
More Details: Iron coordination complexes can be used to gain insight on biologically relevant iron-oxygen compounds generated in iron metalloenzymes. Here, the authors characterise a μ-1,2-hydroperoxo FeIIIFeIII and a μ-1,2-peroxo FeIVFeIII, and study their reactivity in C-H activation.
Document Type: article
File Description: electronic resource
Language: English
ISSN: 2041-1723
Relation: https://doaj.org/toc/2041-1723
DOI: 10.1038/s41467-022-28894-5
Access URL: https://doaj.org/article/e119fe5876634e77868e5b9a13ed59e0
Accession Number: edsdoj.119fe5876634e77868e5b9a13ed59e0
Database: Directory of Open Access Journals
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  Data: Iron coordination complexes can be used to gain insight on biologically relevant iron-oxygen compounds generated in iron metalloenzymes. Here, the authors characterise a μ-1,2-hydroperoxo FeIIIFeIII and a μ-1,2-peroxo FeIVFeIII, and study their reactivity in C-H activation.
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