Nanoscale zero-valent iron supported on carbon nanotubes for polychlorinated biphenyls removal.

Bibliographic Details
Title: Nanoscale zero-valent iron supported on carbon nanotubes for polychlorinated biphenyls removal.
Authors: Xiuqin Cao, Haoran Wang, Chunmiao Yang, Lin Cheng, Kunming Fu, Fuguo Qiu
Source: Desalination & Water Treatment; Oct2020, Vol. 201, p173-186, 14p
Subject Terms: POLYCHLORINATED biphenyls, CARBON nanotubes, X-ray powder diffraction, TRANSMISSION electron microscopy, IRON
Abstract: Nanoscale zero-valent iron (nZVI)-multiwalled carbon nanotube (MWCNT) was first applied to remove polychlorinated biphenyls (PCBs) from water. The characterization result from scanning electron microscopy, transmission electron microscopy, and X-ray powder diffraction showed that the nZVI was immobilized successfully on the surface or into the network of MWCNTs. The effects of different reaction conditions like temperature, initial pH values, MWCNT-nZVI dosage, and initial PCBs concentrations for the removal of PCBs were evaluated. Comparing to pure nZVI or MWCNT, the MWCNT-nZVI nanocomposites exhibited around 30% higher efficiency on PCBs removal. The removal process obeyed the pseudo-secondary-order kinetics model. By calculating the material balance of Cl- during the degradation of PCBs by MWCNT-nZVI, it demonstrated that MWCNT-nZVI has not only a reducing effect but also an adsorption effect on PCBs. During the reaction, reduction plays a dominant role. The reductive activity of nZVI was efficiently supported by MWCNT, which can accelerate electrons transfer in the composite and greatly enhance the reduction activity of nZVI. At the same time, the reusability and stability of MWCNT-nZVI were considered. Overall, MWCNT-nZVI nanocomposites offer a promising alternative material for the removal of PCBs from water. [ABSTRACT FROM AUTHOR]
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Nanoscale zero-valent iron supported on carbon nanotubes for polychlorinated biphenyls removal.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Xiuqin+Cao%22">Xiuqin Cao</searchLink><br /><searchLink fieldCode="AR" term="%22Haoran+Wang%22">Haoran Wang</searchLink><br /><searchLink fieldCode="AR" term="%22Chunmiao+Yang%22">Chunmiao Yang</searchLink><br /><searchLink fieldCode="AR" term="%22Lin+Cheng%22">Lin Cheng</searchLink><br /><searchLink fieldCode="AR" term="%22Kunming+Fu%22">Kunming Fu</searchLink><br /><searchLink fieldCode="AR" term="%22Fuguo+Qiu%22">Fuguo Qiu</searchLink>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: Desalination & Water Treatment; Oct2020, Vol. 201, p173-186, 14p
– Name: Subject
  Label: Subject Terms
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22POLYCHLORINATED+biphenyls%22">POLYCHLORINATED biphenyls</searchLink><br /><searchLink fieldCode="DE" term="%22CARBON+nanotubes%22">CARBON nanotubes</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+powder+diffraction%22">X-ray powder diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22TRANSMISSION+electron+microscopy%22">TRANSMISSION electron microscopy</searchLink><br /><searchLink fieldCode="DE" term="%22IRON%22">IRON</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Nanoscale zero-valent iron (nZVI)-multiwalled carbon nanotube (MWCNT) was first applied to remove polychlorinated biphenyls (PCBs) from water. The characterization result from scanning electron microscopy, transmission electron microscopy, and X-ray powder diffraction showed that the nZVI was immobilized successfully on the surface or into the network of MWCNTs. The effects of different reaction conditions like temperature, initial pH values, MWCNT-nZVI dosage, and initial PCBs concentrations for the removal of PCBs were evaluated. Comparing to pure nZVI or MWCNT, the MWCNT-nZVI nanocomposites exhibited around 30% higher efficiency on PCBs removal. The removal process obeyed the pseudo-secondary-order kinetics model. By calculating the material balance of Cl- during the degradation of PCBs by MWCNT-nZVI, it demonstrated that MWCNT-nZVI has not only a reducing effect but also an adsorption effect on PCBs. During the reaction, reduction plays a dominant role. The reductive activity of nZVI was efficiently supported by MWCNT, which can accelerate electrons transfer in the composite and greatly enhance the reduction activity of nZVI. At the same time, the reusability and stability of MWCNT-nZVI were considered. Overall, MWCNT-nZVI nanocomposites offer a promising alternative material for the removal of PCBs from water. [ABSTRACT FROM AUTHOR]
– Name: Abstract
  Label:
  Group: Ab
  Data: <i>Copyright of Desalination & Water Treatment is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.5004/dwt.2020.26091
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 14
        StartPage: 173
    Subjects:
      – SubjectFull: POLYCHLORINATED biphenyls
        Type: general
      – SubjectFull: CARBON nanotubes
        Type: general
      – SubjectFull: X-ray powder diffraction
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      – SubjectFull: TRANSMISSION electron microscopy
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      – SubjectFull: IRON
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    Titles:
      – TitleFull: Nanoscale zero-valent iron supported on carbon nanotubes for polychlorinated biphenyls removal.
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            NameFull: Xiuqin Cao
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            NameFull: Haoran Wang
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            NameFull: Chunmiao Yang
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            NameFull: Lin Cheng
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            NameFull: Kunming Fu
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              Text: Oct2020
              Type: published
              Y: 2020
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