The Absolute Configurations of Haliclonacyclamines A and B Determined by X-Ray Crystallographic Analysis.
Title: | The Absolute Configurations of Haliclonacyclamines A and B Determined by X-Ray Crystallographic Analysis. |
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Authors: | I. Wayan Mudianta1, Mary J. Garson1, Paul V. Bernhardt1 |
Source: | Australian Journal of Chemistry. Jul2009, Vol. 62 Issue 7, p667-670. 4p. |
Subject Terms: | *ALKALOIDS, *X-ray crystallography, *ENANTIOMERS, *STEREOCHEMISTRY, *PIPERIDINE, *BIOSYNTHESIS, *BIOACTIVE compounds |
Abstract: | X-Ray crystallography establishes that the marine alkaloids (â)-haliclonacyclamine A 1 and ()-haliclonacyclamine B 2 each have the configuration C2 (R), C3 (R), C7 (R), and C9 (R). The alkaloids appear to be enantiomerically pure; this provides an insight into the stereochemical consequences of the biosynthetic pathway leading to these bioactive 3-alkylpiperidine alkaloids. [ABSTRACT FROM AUTHOR] |
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RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1071/CH09128 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 4 StartPage: 667 Subjects: – SubjectFull: ALKALOIDS Type: general – SubjectFull: X-ray crystallography Type: general – SubjectFull: ENANTIOMERS Type: general – SubjectFull: STEREOCHEMISTRY Type: general – SubjectFull: PIPERIDINE Type: general – SubjectFull: BIOSYNTHESIS Type: general – SubjectFull: BIOACTIVE compounds Type: general Titles: – TitleFull: The Absolute Configurations of Haliclonacyclamines A and B Determined by X-Ray Crystallographic Analysis. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: I. Wayan Mudianta – PersonEntity: Name: NameFull: Mary J. Garson – PersonEntity: Name: NameFull: Paul V. Bernhardt IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 07 Text: Jul2009 Type: published Y: 2009 Identifiers: – Type: issn-print Value: 00049425 Numbering: – Type: volume Value: 62 – Type: issue Value: 7 Titles: – TitleFull: Australian Journal of Chemistry Type: main |
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