The Absolute Configurations of Haliclonacyclamines A and B Determined by X-Ray Crystallographic Analysis.

Bibliographic Details
Title: The Absolute Configurations of Haliclonacyclamines A and B Determined by X-Ray Crystallographic Analysis.
Authors: I. Wayan Mudianta1, Mary J. Garson1, Paul V. Bernhardt1
Source: Australian Journal of Chemistry. Jul2009, Vol. 62 Issue 7, p667-670. 4p.
Subject Terms: *ALKALOIDS, *X-ray crystallography, *ENANTIOMERS, *STEREOCHEMISTRY, *PIPERIDINE, *BIOSYNTHESIS, *BIOACTIVE compounds
Abstract: X-Ray crystallography establishes that the marine alkaloids (–)-haliclonacyclamine A 1 and ()-haliclonacyclamine B 2 each have the configuration C2 (R), C3 (R), C7 (R), and C9 (R). The alkaloids appear to be enantiomerically pure; this provides an insight into the stereochemical consequences of the biosynthetic pathway leading to these bioactive 3-alkylpiperidine alkaloids. [ABSTRACT FROM AUTHOR]
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  Data: The Absolute Configurations of Haliclonacyclamines A and B Determined by X-Ray Crystallographic Analysis.
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  Data: <searchLink fieldCode="AR" term="%22I%2E+Wayan+Mudianta%22">I. Wayan Mudianta</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Mary+J%2E+Garson%22">Mary J. Garson</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Paul+V%2E+Bernhardt%22">Paul V. Bernhardt</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Australian+Journal+of+Chemistry%22">Australian Journal of Chemistry</searchLink>. Jul2009, Vol. 62 Issue 7, p667-670. 4p.
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  Data: *<searchLink fieldCode="DE" term="%22ALKALOIDS%22">ALKALOIDS</searchLink><br />*<searchLink fieldCode="DE" term="%22X-ray+crystallography%22">X-ray crystallography</searchLink><br />*<searchLink fieldCode="DE" term="%22ENANTIOMERS%22">ENANTIOMERS</searchLink><br />*<searchLink fieldCode="DE" term="%22STEREOCHEMISTRY%22">STEREOCHEMISTRY</searchLink><br />*<searchLink fieldCode="DE" term="%22PIPERIDINE%22">PIPERIDINE</searchLink><br />*<searchLink fieldCode="DE" term="%22BIOSYNTHESIS%22">BIOSYNTHESIS</searchLink><br />*<searchLink fieldCode="DE" term="%22BIOACTIVE+compounds%22">BIOACTIVE compounds</searchLink>
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  Data: X-Ray crystallography establishes that the marine alkaloids (–)-haliclonacyclamine A 1 and ()-haliclonacyclamine B 2 each have the configuration C2 (R), C3 (R), C7 (R), and C9 (R). The alkaloids appear to be enantiomerically pure; this provides an insight into the stereochemical consequences of the biosynthetic pathway leading to these bioactive 3-alkylpiperidine alkaloids. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Australian Journal of Chemistry is the property of CSIRO Publishing and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1071/CH09128
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      – Code: eng
        Text: English
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        PageCount: 4
        StartPage: 667
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      – SubjectFull: ALKALOIDS
        Type: general
      – SubjectFull: X-ray crystallography
        Type: general
      – SubjectFull: ENANTIOMERS
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      – SubjectFull: STEREOCHEMISTRY
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      – SubjectFull: PIPERIDINE
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      – SubjectFull: BIOSYNTHESIS
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      – SubjectFull: BIOACTIVE compounds
        Type: general
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      – TitleFull: The Absolute Configurations of Haliclonacyclamines A and B Determined by X-Ray Crystallographic Analysis.
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            NameFull: I. Wayan Mudianta
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            NameFull: Mary J. Garson
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            NameFull: Paul V. Bernhardt
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            – D: 01
              M: 07
              Text: Jul2009
              Type: published
              Y: 2009
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            – TitleFull: Australian Journal of Chemistry
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