Bibliographic Details
| Title: |
Regiospecific Alkene Oxyamination via N‐Alkylation‐ Hydroxylation‐Transesterification Cascades. |
| Authors: |
Zhang, Hong‐Xia1 (AUTHOR), Kou, Li‐Gang1 (AUTHOR), Gao, Ya‐Ru1 (AUTHOR), Jia, Qiong1 (AUTHOR), Wang, Yong‐Qiang1 (AUTHOR) wangyq@nwu.edu.cn |
| Source: |
Advanced Synthesis & Catalysis. 3/18/2025, Vol. 367 Issue 6, p1-5. 5p. |
| Abstract: |
An unprecedented cascade reaction of simple inactive alkenes, azo compounds and H2O to produce valuable poly‐substituted oxazolidinones is reported herein. The transformation possesses exclusive regioselectivity and features mild reaction conditions and a broad substrate scope. Mechanistic studies indicated this transformation underwent a N‐alkylation‐hydroxylation‐transesterification cascade process. This research not only pushes the boundaries of the essential difunctionalization of alkenes but also exploits a new chemistry for azo compounds. [ABSTRACT FROM AUTHOR] |
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| Database: |
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