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Nanoengineering Metal–Organic Frameworks and Derivatives for Electrosynthesis of Ammonia.

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Title: Nanoengineering Metal–Organic Frameworks and Derivatives for Electrosynthesis of Ammonia.
Authors: Feng, Daming1 (AUTHOR), Zhou, Lixue1 (AUTHOR), White, Timothy J.2 (AUTHOR), Cheetham, Anthony K.3 (AUTHOR), Ma, Tianyi4 (AUTHOR) tianyi.ma@rmit.edu.au, Wei, Fengxia5 (AUTHOR) wei_fengxia@imre.a-star.edu.sg
Source: Nano-Micro Letters. 8/24/2023, Vol. 15 Issue 1, p1-36. 36p.
Subject Terms: *METAL-organic frameworks, *OXYGEN reduction, *NANOTECHNOLOGY, *ELECTROSYNTHESIS, *ELECTROCATALYSTS, *ARTIFICIAL intelligence, *ELECTROCATALYSIS
Abstract: Highlights: Recent advances in the metal–organic framework (MOF)-related catalysts for electrochemical ammonia synthesis protocols under ambient reaction conditions are summarized and discussed. The design and fabrication of efficient electrocatalysts from MOF for the reduction of N2 and NO3− are systematically analyzed. Based on the current advances, the ongoing challenges and promising perspectives are highlighted. Electrocatalytic synthesis under mild conditions has become increasingly important as one of the practical alternatives for industrial applications, especially for the green ammonia (NH3) industry. A properly engineered electrocatalyst plays a vital role in the realization of superior catalytic performance. Among various types of promising nanomaterials, metal–organic frameworks (MOFs) are competitive candidates for developing efficient electrocatalytic NH3 synthesis from simple nitrogen-containing molecules or ions, such as N2 and NO3−. In this review, recent advances in the development of electrocatalysts derived from MOFs for the electrosynthesis of NH3 are collected, categorized, and discussed, including their application in the N2 reduction reaction (NRR) and the NO3− reduction reaction (NO3RR). Firstly, the fundamental principles are illustrated, such as plausible mechanisms of NH3 generation from N2 and NO3−, the apparatus of corresponding electrocatalysis, parameters for evaluation of reaction efficiency, and detection methods of yielding NH3. Then, the electrocatalysts for NRR processes are discussed in detail, including pristine MOFs, MOF-hybrids, MOF-derived N-doped porous carbons, single atomic catalysts from pyrolysis of MOFs, and other MOF-related materials. Subsequently, MOF-related NO3RR processes are also listed and discussed. Finally, the existing challenges and prospects for the rational design and fabrication of electrocatalysts from MOFs for electrochemical NH3 synthesis are presented, such as the evolution of investigation methods with artificial intelligence, innovation in synthetic methods of MOF-related catalysts, advancement of characterization techniques, and extended electrocatalytic reactions. [ABSTRACT FROM AUTHOR]
Copyright of Nano-Micro Letters is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Nanoengineering Metal–Organic Frameworks and Derivatives for Electrosynthesis of Ammonia.
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  Data: Highlights: Recent advances in the metal–organic framework (MOF)-related catalysts for electrochemical ammonia synthesis protocols under ambient reaction conditions are summarized and discussed. The design and fabrication of efficient electrocatalysts from MOF for the reduction of N2 and NO3− are systematically analyzed. Based on the current advances, the ongoing challenges and promising perspectives are highlighted. Electrocatalytic synthesis under mild conditions has become increasingly important as one of the practical alternatives for industrial applications, especially for the green ammonia (NH3) industry. A properly engineered electrocatalyst plays a vital role in the realization of superior catalytic performance. Among various types of promising nanomaterials, metal–organic frameworks (MOFs) are competitive candidates for developing efficient electrocatalytic NH3 synthesis from simple nitrogen-containing molecules or ions, such as N2 and NO3−. In this review, recent advances in the development of electrocatalysts derived from MOFs for the electrosynthesis of NH3 are collected, categorized, and discussed, including their application in the N2 reduction reaction (NRR) and the NO3− reduction reaction (NO3RR). Firstly, the fundamental principles are illustrated, such as plausible mechanisms of NH3 generation from N2 and NO3−, the apparatus of corresponding electrocatalysis, parameters for evaluation of reaction efficiency, and detection methods of yielding NH3. Then, the electrocatalysts for NRR processes are discussed in detail, including pristine MOFs, MOF-hybrids, MOF-derived N-doped porous carbons, single atomic catalysts from pyrolysis of MOFs, and other MOF-related materials. Subsequently, MOF-related NO3RR processes are also listed and discussed. Finally, the existing challenges and prospects for the rational design and fabrication of electrocatalysts from MOFs for electrochemical NH3 synthesis are presented, such as the evolution of investigation methods with artificial intelligence, innovation in synthetic methods of MOF-related catalysts, advancement of characterization techniques, and extended electrocatalytic reactions. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Nano-Micro Letters is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1007/s40820-023-01169-4
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        Text: English
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      – SubjectFull: METAL-organic frameworks
        Type: general
      – SubjectFull: OXYGEN reduction
        Type: general
      – SubjectFull: NANOTECHNOLOGY
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      – SubjectFull: ELECTROSYNTHESIS
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      – TitleFull: Nanoengineering Metal–Organic Frameworks and Derivatives for Electrosynthesis of Ammonia.
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              M: 08
              Text: 8/24/2023
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              Y: 2023
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