Recent advances in antiaromatic metallacycles.

Authors: Li, Lei¹ (AUTHOR), Li, Yang² (AUTHOR), Jiang, Wenfeng¹ (AUTHOR), Bai, Wei¹ (AUTHOR) baiwei@dlut.edu.cn

Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 3/21/2025, Vol. 54 Issue 11, p4432-4436. 5p.

Subject Terms: *AROMATICITY, *ORGANOMETALLIC chemistry, *CHEMICAL amplification, *METALLACYCLES, *CHEMICAL bond lengths

Synthesis, Characterization and Reactivity of a Base‐Stabilized Dialane(4) Supported by Double Layer Nitrogen–Phosphorus Ligands.

Authors: Chen, Pengfei¹ (AUTHOR), Li, Yafei¹ (AUTHOR), Zhao, Qianyi² (AUTHOR), Zhu, Congqing¹ (AUTHOR), Zhu, Qin¹ (AUTHOR) zhuqin@nju.edu.cn

Source: Chinese Journal of Chemistry. 3/15/2025, Vol. 43 Issue 6, p627-632. 6p.

Subject Terms: *ORGANOMETALLIC chemistry, *REACTIVITY (Chemistry), *SCISSION (Chemistry), *COORDINATION compounds, *OXIDATIVE addition, *INTERMEDIATES (Chemistry), *ALUMINUM hydride

Efficient Self‐assembly of Isoquinoline‐Based Triply Interlocked Cages.

Authors: Mu, Qiu‐Shui¹, Wang, Xin‐Yu¹, Gao, Xiang¹, Jin, Guo‐Xin¹, gxjin@fudan.edu.cn

Source: Chinese Journal of Chemistry; 3/15/2025, Vol. 43 Issue 6, p607-612, 6p

Generation of high nuclearity silver(I) and gold(I) species using simple N-heterocyclic carbene complexes.

Authors: Yousefshahi, Mohammad Reza¹ (AUTHOR), Neshat, Abdollah¹ (AUTHOR) a.neshat@iasbs.ac.ir, Tahmasebi, Elham¹ (AUTHOR), Eigner, Vaclav² (AUTHOR), Dusek, Michal² (AUTHOR), Osanlou, Farzaneh³ (AUTHOR)

Source: New Journal of Chemistry. 2/28/2025, Vol. 49 Issue 8, p3328-3333. 6p.

Subject Terms: *ATOMIC absorption spectroscopy, *ORGANOMETALLIC chemistry, *NUCLEAR magnetic resonance spectroscopy, *LIGANDS (Chemistry), *X-ray diffraction

A Redox‐active Cyclometalated Platinum Ring Enables Synthetic Post‐processing of a [2]Rotaxane.

Authors: Kandel, Raksha¹, Soto, Miguel A.¹, Medina, Daniel¹, Patrick, Brian O.¹, Lelj, Francesco², MacLachlan, Mark J.^1,3,4, mmaclach@chem.ubc.ca

Source: Angewandte Chemie; 1/15/2025, Vol. 137 Issue 3, p1-7, 7p

Karl Ziegler – Early Career of a Scientist.

Authors: Kießling, Christoph¹, christophkiessling@web.de

Source: Angewandte Chemie International Edition; Jan2025, Vol. 64 Issue 1, p1-9, 9p

Au(III) π‐Allyl Complexes: Synthesis, Structure, Reactivity, and Catalytic Applications.

Authors: Vesseur, David¹ (AUTHOR), Holmsen, Marte S. M.^1,2,3 (AUTHOR), Bourissou, Didier¹ (AUTHOR) didier.bourissou@univ-tlse3.fr

Source: ChemCatChem. 10/20/2023, Vol. 15 Issue 20, p1-9. 9p.

Subject Terms: *HOMOGENEOUS catalysis, *ORGANOMETALLIC chemistry, *TRANSITION metal complexes, *PALLADIUM

[IPr # –PEPPSI]: A Well-Defined, Highly Hindered and Broadly Applicable Pd(II)–NHC (NHC = N-Heterocyclic Carbene) Precatalyst for Cross-Coupling Reactions.

Authors: Rahman, Md. Mahbubur¹ (AUTHOR) rahman.mm11@gmail.com, Zhao, Qun^1,2 (AUTHOR) qzhao23@jhu.edu, Meng, Guangrong¹ (AUTHOR) gmeng@scripps.edu, Lalancette, Roger¹ (AUTHOR) roger.lalancette@gmail.com, Szostak, Roman³ (AUTHOR) roman.szostak@chem.uni.wroc.pl, Szostak, Michal¹ (AUTHOR) michal.szostak@rutgers.edu

Source: Molecules. Aug2023, Vol. 28 Issue 15, p5833. 13p.

Subject Terms: *ORGANOMETALLIC chemistry, *CHEMOSELECTIVITY, *PYRIDINE, *LIGANDS (Biochemistry), *CATALYSTS, *SONOGASHIRA reaction, *SUZUKI reaction

Geographic Terms: BURLINGTON (Vt.), CANADA

Electrochemical Synthesis of Metal Complexes Using Dissolving Anodes.

Authors: Nicholls, Thomas P.¹ (AUTHOR) thomas.nicholls@flinders.edu.au, Jia, Zhongfan¹ (AUTHOR), Chalker, Justin M.¹ (AUTHOR)

Source: Chemistry - A European Journal. 12/18/2024, Vol. 30 Issue 71, p1-8. 8p.

Subject Terms: *INORGANIC chemistry, *ORGANOMETALLIC chemistry, *METAL complexes, *ELECTROCHEMICAL electrodes, *PRODUCTION methods

Chemistry of organometallic nucleic acid components: personal perspectives and prospects for the future.

Authors: Klarek, Mateusz¹ (AUTHOR), Kowalski, Konrad¹ (AUTHOR) konrad.kowalski@chemia.uni.lodz.pl

Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 12/14/2024, Vol. 53 Issue 46, p18420-18439. 20p.

Subject Terms: *BIOCHEMISTRY, *ORGANOMETALLIC chemistry, *NUCLEIC acids, *SPACE exploration, *DOSAGE forms of drugs, *RING formation (Chemistry)

Reversible Grafting in Surface Organometallic Chemistry with a Late Transition‐Metal Amidinate Precursor.

Authors: Ehinger, Christian¹ (AUTHOR), Copéret, Christophe¹ (AUTHOR) ccoperet@ethz.ch

Source: Helvetica Chimica Acta. Dec2024, Vol. 107 Issue 12, p1-6. 6p.

Subject Terms: *SURFACE chemistry, *ORGANOMETALLIC chemistry, *MANUFACTURING processes, *NUCLEAR magnetic resonance spectroscopy, *HIGH temperatures

The Role of L‐Ligands in Silica‐Supported Ti Oxo/Imido Heterometathesis Catalysts.

Authors: Bushkov, Nikolai S.¹ (AUTHOR), Rumyantsev, Andrey V.^1,2 (AUTHOR), Pichugov, Andrey V.¹ (AUTHOR), Zhizhin, Anton A.¹ (AUTHOR), Aleshin, Dmitry Yu.³ (AUTHOR), Gutsul, Evgenii I.¹ (AUTHOR), Takazova, Rina U.¹ (AUTHOR), Kitaeva, Dinara Kh.¹ (AUTHOR), Dolgushin, Fedor M.³ (AUTHOR), Novikov, Roman A.⁴ (AUTHOR), Zhizhko, Pavel A.¹ (AUTHOR) zhizhko@ineos.ac.ru, Zarubin, Dmitry N.¹ (AUTHOR) zaroubine@ineos.ac.ru

Source: Applied Organometallic Chemistry. Dec2024, Vol. 38 Issue 12, p1-9. 9p.

Subject Terms: *SURFACE chemistry, *ORGANOMETALLIC chemistry, *PYRIDINE, *CATALYSTS, *TITANIUM, *METATHESIS reactions

Electronic Structures of Late versus Early Transition Metal Imido Complexes from 15N‐NMR Signatures.

Authors: Kakiuchi, Yuya¹, Copéret, Christophe¹, ccoperet@ethz.ch

Source: Helvetica Chimica Acta; Nov2024, Vol. 107 Issue 11, p1-10, 10p

Flexible Coordination of SacNac Ligands in Iridium Complexes and their Application to Catalytic Hydroboration.

Authors: Rangel‐Garcia, Jesus¹, E. Rivas, Christopher¹, González‐García, Gerardo¹, Campos, Jesús², jesus.campos@iiq.csic.es, Serrano, Oracio¹, oraciosinh@ugto.mx, Cristobal, Crispin¹, cs.cristobal@ugto.mx

Source: European Journal of Inorganic Chemistry; 10/25/2024, Vol. 27 Issue 30, p1-10, 10p

Heavier tetrylene- and tetrylyne-transition metal chemistry: it's no carbon copy.

Authors: Hadlington, Terrance J.¹ (AUTHOR) terrance.hadilngton@tum.de

Source: Chemical Society Reviews. 10/7/2024, Vol. 53 Issue 19, p9738-9831. 94p.

Subject Terms: *ORGANOMETALLIC chemistry, *NINETEENTH century, *CATALYSIS, *METALS, *CARBON

Post‐assembly modification of discrete poly‐NHC‐derived organometallic assemblies.

Authors: Ma, Li‐Li¹ (AUTHOR), An, Yuan‐Yuan¹ (AUTHOR), Zhang, Ya‐Wen¹ (AUTHOR), Li, Yang¹ (AUTHOR), Zhang, Le¹ (AUTHOR), Han, Ying‐Feng¹ (AUTHOR) yfhan@nwu.edu.cn

Source: Applied Organometallic Chemistry. Oct2024, Vol. 38 Issue 10, p1-12. 12p.

Subject Terms: *ORGANOMETALLIC chemistry, *CHEMICAL reactions, *GOLD, *OXIDIZING agents, *IODINE

Reactions of Cyclic Acetals with Organoelement Compounds.

Authors: Mikhailova, N. N.¹ ximik2008@mail.ru, Shavshukova, S. Yu.¹, Gasan-Zade, E. I.¹, Zlotskii, S. S.¹

Source: Russian Journal of General Chemistry. Mar2023, Vol. 93 Issue 3, p760-765. 6p.

Subject Terms: *ORGANOMETALLIC chemistry, *GRIGNARD reagents

Geographic Terms: BASHKORTOSTAN (Russia)

Company/Entity: CALIFORNIA Academy of Sciences (San Francisco, Calif.)

Ag–NHC Complexes in the π-Activation of Alkynes.

Authors: Yang, Shiyi¹ (AUTHOR), Zhou, Tongliang¹ (AUTHOR), Yu, Xiang¹ (AUTHOR), Szostak, Michal¹ (AUTHOR) michal.szostak@rutgers.edu

Source: Molecules. Feb2023, Vol. 28 Issue 3, p950. 21p.

Subject Terms: *ALKYNES, *ORGANOMETALLIC chemistry, *ORGANIC synthesis, *BEDROCK, *LIGANDS (Biochemistry), *CARBENE synthesis

Flow Chemistry of Metal Carbenoid Species towards Selective Organic Synthesis.

Authors: Okamoto, Kazuhiro¹ (AUTHOR) kokamoto@sci.hokudai.ac.jp, Nagaki, Aiichiro¹ (AUTHOR) nagaki@sci.hokudai.ac.jp

Source: Synthesis. Sep2024, Vol. 56 Issue 18, p2899-2908. 10p.

Subject Terms: *FLOW chemistry, *ORGANOMETALLIC chemistry, *TEMPERATURE control, *ORGANIC synthesis, *CYCLOPROPANATION

The First Discovery of Spherical Carborane Molecular Ferroelectric Crystals.

Authors: Guo, Wenjing¹, Yang, Zhao¹, Shu, Longlong², llshu@ncu.edu.cn, Cai, Hu¹, caihu@ncu.edu.cn, Wei, Zhenhong¹, weizh@ncu.edu.cn

Source: Angewandte Chemie International Edition; 9/2/2024, Vol. 63 Issue 36, p1-7, 7p