Hydrogenases - Types, Sources, Properties, and the Potential for Their Application.

Alternate Title: Hidrogenaze - tipovi, izvori, svojstva i potencijal njihove primjene.

Authors: Marić, A.-K.¹, Radan, A.¹, Milčić, N.¹, Sudar, M.¹, Blažević, Z. Findrik¹ zfindrik@fkit.unizg.hr

Source: Kemija u Industriji. 2025, Vol. 74 Issue 1/2, p33-42. 10p.

Subject Terms: *METALLOENZYMES, *HYDROGENASE, *HYDROGEN production, *BIOCHEMICAL substrates, *ENZYMES

Artificial Gold Enzymes Using a Genetically Encoded Thiophenol‐Based Noble‐Metal‐Binding Ligand.

Authors: Veen, Mathijs J.¹, Aalbers, Friso S.¹, Rozeboom, Henriëtte J.², Thunnissen, Andy‐Mark W. H.², Sauer, Daniel F.¹, danielsa@miltenyi.com, Roelfes, Gerard¹, J.G.Roelfes@rug.nl

Source: Angewandte Chemie; 3/17/2025, Vol. 137 Issue 12, p1-9, 9p

Mesoporous Electrodes Enhance the Electrocatalytic Performance of [FeFe]‐Hydrogenase.

Authors: Webb, Sophie^1,2, Veliju, Astrit³, Maroni, Plinio¹, Apfel, Ulf‐Peter^4,5, Happe, Thomas³, Milton, Ross D.^1,2, ross.milton@unige.ch

Source: Angewandte Chemie; 1/27/2025, Vol. 137 Issue 5, p1-9, 9p

Tungsten is utilized for lactate consumption and SCFA production by a dominant human gut microbe Eubacterium limosum.

Authors: Putumbaka, Saisuki¹, Schut, Gerrit J.¹, Thorgersen, Michael P.¹, Poole, Farris L.¹, Shao, Nana¹, Rodionov, Dmitry A.², Adams, Michael W. W.¹, adamsm@uga.edu

Source: Proceedings of the National Academy of Sciences of the United States of America; 1/7/2025, Vol. 122 Issue 1, p1-32, 42p

Colorimetric Detection of Ferulic Acid by Nitrogen–Phosphorus Double-Doped Porous Metalloenzymes.

Authors: Ruixue Zhao¹ (AUTHOR), Xue, Yuting¹ (AUTHOR), Yu, Yue¹ (AUTHOR), Zhong, Haotian¹ (AUTHOR), Liu, Bin¹ (AUTHOR), Chen, Zhengbo¹ (AUTHOR) czb979216@sina.com, Li, Kai¹ (AUTHOR), Zheng, Lirong² (AUTHOR), Zuo, Xia¹ (AUTHOR) zuoxia@cnu.edu.cn

Source: Journal of Analytical Chemistry. Nov2023, Vol. 78 Issue 11, p1492-1501. 10p.

Subject Terms: *FERULIC acid, *METALLOENZYMES, *POROUS materials, *HYDROXYL group, *HYDROGEN peroxide, *PHOSPHORUS

Structural and reactivity insights into high-valent Co(III)–(μ-peroxo)–Co(IV) and its electromer Co(III)–(μ-superoxo)–Co(III).

Authors: Sharma, Parkhi¹ (AUTHOR), Gupta, Sikha¹ (AUTHOR), Kumar, Rakesh¹ (AUTHOR), Charisiadis, Asterios² (AUTHOR), Sauvan, Maxime² (AUTHOR), Velasco, Lucia² (AUTHOR), Saini, Abhishek³ (AUTHOR), Moonshiram, Dooshaye² (AUTHOR) dooshaye.moonshiram@csic.es, Draksharapu, Apparao¹ (AUTHOR) appud@iitk.ac.in

Source: Chemical Communications. 12/25/2024, Vol. 60 Issue 99, p14846-14849. 4p.

Subject Terms: *OXIDATION of water, *METALLOENZYMES, *CATALYSIS

Copper Complexes with Protein‐Based N‐Donor Ligands as cis‐Selective Nascent Cyclopropanases.

Authors: Fujieda, Nobutaka¹, fujieda@omu.ac.jp, Matsuo, Atsuki², Itoh, Shinobu², shinobu@mls.eng.osaka-u.ac.jp

Source: Chemistry - A European Journal; 12/13/2024, Vol. 30 Issue 70, p1-5, 5p

Molecularly Imprinted Polymers for Highly Specific Bioorthogonal Catalysis Inside Cells.

Authors: Gao, Zhiguo^1,2, Shao, Quanlin², Xing, Jiaqi², Liang, Yi², Meng, Fanzhen², Chen, Jian¹, He, Wei², hewei322@cpu.edu.cn, Li, Yaojia³, liyaojia@xxmu.edu.cn, Sun, Baiwang¹, chmsunbw@seu.edu.cn

Source: Angewandte Chemie International Edition; Dec2024, Vol. 63 Issue 49, p1-7, 7p

Microenvironment‐Adaptive Metallo‐Polymeric Nanodecoys via Subcomponent Coordination for Bacterial Biofilm Eradication and Immunomodulation.

Authors: Li, Yuanfeng¹, Hua, Lei^1,2, He, Wei^1,2, Chen, Lei^1,2, Piao, Yinzi^1,2, Peng, Mengna^1,2, Li, Dongdong², ldd@ucas.ac.cn, Shi, Linqi^1,3, Liu, Yong^1,2,3, y.liu@ucas.ac.cn

Source: Advanced Functional Materials; 10/29/2024, Vol. 34 Issue 44, p1-12, 12p

Light‐Induced Electron Transfer in a [NiFe] Hydrogenase Opens a Photochemical Shortcut for Catalytic Dihydrogen Cleavage.

Authors: Karafoulidi‐Retsou, Chara¹ (AUTHOR), Lorent, Christian¹ (AUTHOR), Katz, Sagie¹ (AUTHOR), Rippers, Yvonne² (AUTHOR), Matsuura, Hiroaki³ (AUTHOR), Higuchi, Yoshiki⁴ (AUTHOR), Zebger, Ingo¹ (AUTHOR) ingo.zebger@tu-berlin.de, Horch, Marius² (AUTHOR) marius.horch@fu-berlin.de

Source: Angewandte Chemie International Edition. 10/21/2024, Vol. 63 Issue 43, p1-5. 5p.

Subject Terms: *THERMAL electrons, *METALLOENZYMES, *ELECTRON paramagnetic resonance spectroscopy, *EINSTEIN-Podolsky-Rosen experiment, *CHARGE exchange, *IRON

Enzyme Machinery for Bacterial Glucoside Metabolism through a Conserved Non‐hydrolytic Pathway.

Authors: Kastner, Klara¹, Bitter, Johannes¹, Pfeiffer, Martin¹, Grininger, Christoph², Oberdorfer, Gustav^3,4, Pavkov‐Keller, Tea^2,4,5, Weber, Hansjörg⁶, Nidetzky, Bernd^1,7, bernd.nidetzky@tugraz.at

Source: Angewandte Chemie International Edition; 10/21/2024, Vol. 63 Issue 43, p1-8, 8p

Targeting Metalloenzymes: The "Achilles' Heel" of Viruses and Parasites.

Authors: Moianos, Dimitrios¹ (AUTHOR) moianosjim@gmail.com, Prifti, Georgia-Myrto¹ (AUTHOR), Makri, Maria¹ (AUTHOR), Zoidis, Grigoris¹ (AUTHOR) zoidis@pharm.uoa.gr

Source: Pharmaceuticals (14248247). Jun2023, Vol. 16 Issue 6, p901. 31p.

Subject Terms: *METALLOENZYMES, *HIV, *TRYPANOSOMA brucei, *HEPATITIS B, *PROTEOLYSIS, *PARASITES, *HEPATITIS B virus, *PLANT viruses

Recent Theoretical Insights into the Oxidative Degradation of Biopolymers and Plastics by Metalloenzymes †.

Authors: Rovaletti, Anna¹ (AUTHOR), De Gioia, Luca² (AUTHOR), Fantucci, Piercarlo² (AUTHOR), Greco, Claudio¹ (AUTHOR), Vertemara, Jacopo² (AUTHOR), Zampella, Giuseppe² (AUTHOR), Arrigoni, Federica² (AUTHOR) federica.arrigoni@unimib.it, Bertini, Luca² (AUTHOR) federica.arrigoni@unimib.it

Source: International Journal of Molecular Sciences. Apr2023, Vol. 24 Issue 7, p6368. 45p.

Subject Terms: *METALLOENZYMES, *MOLECULAR dynamics, *PLASTICS, *PEROXIDASE, *POLYSACCHARIDES, *LACCASE, *BIOPOLYMERS

Non-Noble Metal Aromatic Oxidation Catalysis: From Metalloenzymes to Synthetic Complexes.

Authors: Masferrer-Rius, Eduard¹ (AUTHOR), Klein Gebbink, Robertus J. M.¹ (AUTHOR) r.j.m.kleingebbink@uu.nl

Source: Catalysts (2073-4344). Apr2023, Vol. 13 Issue 4, p773. 53p.

Subject Terms: *METALLOENZYMES, *MULTIENZYME complexes, *METALS, *METAL catalysts, *CHEMICAL industry

Redox Engineering of Myoglobin by Cofactor Substitution to Enhance Cyclopropanation Reactivity.

Authors: Kagawa, Yoshiyuki¹, Oohora, Koji^1,2, oohora@chem.eng.osaka-u.ac.jp, Himiyama, Tomoki³, Suzuki, Akihiro⁴, Hayashi, Takashi¹, thayashi@chem.eng.osaka-u.ac.jp

Source: Angewandte Chemie; 9/2/2024, Vol. 136 Issue 36, p1-10, 10p

A growth-based screening strategy for engineering the catalytic activity of an oxygen-sensitive formate dehydrogenase.

Authors: Feilong Li^1,2, Scheller, Silvan¹, Lienemann, Michael² Michael.lienemann@vtt.fi

Source: Applied & Environmental Microbiology. Sep2024, Vol. 90 Issue 9, p1-16. 16p.

Subject Terms: *ESCHERICHIA coli, *METALLOENZYMES, *CATALYTIC activity, *HYDROGENASE, *DEHYDROGENASES

An alcove at the acetyl-CoA synthase nickel active site is required for productive substrate CO binding and anaerobic carbon fixation.

Authors: Wiley, Seth¹, Griffith, Claire¹, Eckert, Peter², Mueller, Alexander P.³, Nogle, Robert³, Simpson, Séan D.³, Köpke, Michael³, Can, Mehmet¹, Sarangi, Ritimukta⁴, Kubarych, Kevin², Ragsdale, Stephen W.¹ sragsdal@umich.edu

Source: Journal of Biological Chemistry. Aug2024, Vol. 300 Issue 8, p1-15. 15p.

Subject Terms: *CARBON fixation, *METALLOENZYMES, *CATALYSIS, *NICKEL, *ENZYMES, *ACETYLCOENZYME A

Rationalization of a Streptavidin Based Enantioselective Artificial Suzukiase: An Integrative Computational Approach.

Authors: Tiessler‐Sala, Laura¹, Maréchal, Jean‐Didier¹, jeandidier.marechal@gmail.com, Lledós, Agustí¹, agusti.lledos@uab.cat

Source: Chemistry - A European Journal; Jul2024, Vol. 30 Issue 39, p1-13, 13p

Self-Assembly of Benzyloxycarbonyl Histidine with Zinc Ions for the Construction of Esterase Mimics.

Authors: Sun, Jiacheng^1,2,3,4 (AUTHOR) sunjc_31@tju.edu.cn, Guo, Jingjing⁵ (AUTHOR) Guojingjing@lfnu.edu.cn, Liu, Ling^1,2,3,4 (AUTHOR) liuling_111@tju.edu.cn, Liu, Yu^1,2,3,4 (AUTHOR) liuyuyu@tju.edu.cn, Yu, Linling^1,2,3,4 (AUTHOR) ysun@tju.edu.cn, Sun, Yan^1,2,3,4 (AUTHOR)

Source: Catalysts (2073-4344). Feb2025, Vol. 15 Issue 2, p185. 19p.

Subject Terms: *AMINO acid derivatives, *ORGANIC solvents, *METALLOENZYMES, *IONIC strength, *INDUSTRIAL capacity, *ZINC ions

Enhancing the Anticancer Potential of Targeting Tumor-Associated Metalloenzymes via VEGFR Inhibition by New Triazolo[4,3- a ]pyrimidinone Acyclo C-Nucleosides Multitarget Agents.

Authors: Abd Al Moaty, Mohamed Nabil¹ (AUTHOR) mohamednabil_sc_chem@yahoo.com, El Ashry, El Sayed Helmy¹ (AUTHOR) eelashry60@hotmail.com, Awad, Laila Fathy¹ (AUTHOR) laila.fathy@yahoo.com, Ibrahim, Nihal Ahmed¹ (AUTHOR), Abu-Serie, Marwa Muhammad² (AUTHOR) marwaelhedaia@gmail.com, Barakat, Assem³ (AUTHOR) laila.fathy@yahoo.com, Altowyan, Mezna Saleh⁴ (AUTHOR) msaltowyan@pnu.edu.sa, Teleb, Mohamed⁵ (AUTHOR) mohamed.t.ismail@alexu.edu.eg

Source: Molecules. Apr2022, Vol. 27 Issue 8, pN.PAG-N.PAG. 28p.

Subject Terms: *METALLOENZYMES, *BINDING sites, *MOLECULAR docking, *CANCER invasiveness, *CELLULAR signal transduction