Showing 1 - 11 results of 11 Refine Results
  1. 1
  2. 2
    Periodical

    Molecular investigation of the multi-phase photochemistry of Fe(iii)–citrate in aqueous solutionElectronic supplementary information (ESI) available: Appendix A and Fig. S1 describe the transient optical and photochemical experimental setup of this study; Appendix B and Fig. S2 describe chemical actinometry experiments and relevant calculations; Appendix C describes detailed direct infusion-HRMS parameters; Appendixes D, E, F, G, and H describe the formal kinetic modelling, quantum yields, particle size distributions, atmospheric scaling, and TUV model calculations and selected parameters, respectively. Fig. S3 illustrates experimental quantitation of dissolved Fe2+ and calibration curves of FeII–phenanthroline complexes; Fig. S4 illustrates selected ion chromatograms (SIC's) of FeIII–citrate complex ions; Fig. S5 and S6 describe DI-HRMS screening and MS2 experiments of FeIII–citrate complexes for identification and structural characterization. Fig. S7 illustrates SIC's for FeIII/II–citrate complexes detected in HPLC-HRMS. Fig. S8 shows in situ FlowCam Nano images of colloidal particles. Fig. S9 shows mass size distributions of colloids detected by FlowCam Nano. Fig. S10 and S11 illustrate DI-HRMS results of dissolved colloidal products under specified conditions. Fig. S12 shows the UV-visible spectrum of ferric oxalate photolysis. The list of all molecular assignments in HPLC-PDA-HRMS and DI-HRMS is reported in Tables S1–S3. See https://doi.org/10.1039/d1em00503k

    Source: Environmental science.Processes & impacts. 25(2):190-213

  3. 3
  4. 4
  5. 5
  6. 6
  7. 7
  8. 8
  9. 9
  10. 10
  11. 11